{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679638073728.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.2116/bunsekikagaku.66.39"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"027844021"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/027844021"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I027844021"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/bunsekikagaku/66/1/66_39/_pdf"}},{"identifier":{"@type":"NAID","@value":"130005313296"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"ja","@value":"黒色ポリエステル繊維製品から抽出された分散染料の分析と異同識別"},{"@language":"en","@value":"Analysis and Discrimination of Disperse Dyes Extracted from Black Polyester Fibers"},{"@language":"ja-Kana","@value":"コクショク ポリエステル センイ セイヒン カラ チュウシュツ サレタ ブンサン センリョウ ノ ブンセキ ト イドウ シキベツ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The extracted dyes for polyester fibers from 50 black glove textiles, which are commercialized, were analyzed by liquid chromatography/-linear ion-trap tandem mass spectrometry (LC/LIT-MS<sup>n</sup>).    The identification of dyes was carried out using the custom-built database.    Thirty kinds of disperse dyes were detected from 50 black polyester fibers.    It was found that 5 kinds of disperse dyes on the average were used to dye the textiles with black color and that four kinds of disperse dyes, Disperse Violet 93 : 1, Disperse Orange 288 {Disperse Blue 291 : 1 and an unknown dye [basepeak ion (<i>m/z</i>) = 489, λ<sub>max</sub>: 590 nm]} were more commonly used for the dying compared with other dyes.    The analytical results obtained by LC/LIT-MS<sup>n</sup> allows the discrimination of 1195 pairs (97.6 %) out of 1225 ones.    The discrimination was improved to 99.2 % by the combination of LC/LIT-MS<sup>n</sup> and microspectrophotometry (MSP), although the discriminate rate was 95.9 % when the MPS method was only used."},{"@language":"ja","@value":"液体クロマトグラフィー/リニアイオントラップ型質量分析法（LC/LIT-MS<sup>n</sup>）を用いて，市販の黒色ポリエステル繊維製品50種の染色に使用されている分散染料抽出物を分析した．染料種の特定は，著者らが構築した同装置付属の染料データベースで行った．その結果，30種類の分散染料が確認され，一製品からは平均で約5種類の分散染料が混合物として検出された．また，Disperse Violet 93 : 1，Disperse Orange 288，Disperse Blue 291 : 1及びUnknown［basepeak ion (<i>m/z</i>) ＝489, λ<sub>max</sub>: 590 nm］の4種の分散染料が高い頻度で使用されていた．検出された染料種の組み合わせを指標にして50試料間の異同識別を行ったところ，1225組中1195（97.6％）組が識別可能であった．顕微分光分析法（MSP）により同じ50種の黒色ポリエステル繊維を同様に識別したところ，識別率は95.9％ であったが，更にLC/LIT-MSnによる染料特定法を組み合わせると，識別率は99.2％ に向上した．"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410282679638073729","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000345347352"}],"foaf:name":[{"@language":"ja","@value":"加藤 貴雄"},{"@language":"en","@value":"KATO Takao"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Criminal Investigation Laboratory, Shimane Prefectural Police H.Q."},{"@language":"ja","@value":"島根県刑事部科学捜査研究所"},{"@language":"en","@value":"Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University"},{"@language":"ja","@value":"島根大学大学院総合理工学研究科"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282679638073728","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000345347353"}],"foaf:name":[{"@language":"ja","@value":"鈴木 康弘"},{"@language":"en","@value":"SUZUKI Yasuhiro"}],"jpcoar:affiliationName":[{"@language":"en","@value":"National Research Institute of Police Science"},{"@language":"ja","@value":"科学警察研究所"}]},{"@id":"https://cir.nii.ac.jp/crid/1420282801189126784","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70208700"},{"@type":"NRID","@value":"1000070208700"},{"@type":"NRID","@value":"9000021897703"},{"@type":"NRID","@value":"9000021824813"},{"@type":"NRID","@value":"9000258219148"},{"@type":"NRID","@value":"9000021862842"},{"@type":"NRID","@value":"9000315141962"},{"@type":"NRID","@value":"9000398134483"},{"@type":"NRID","@value":"9000255697350"},{"@type":"NRID","@value":"9000283626501"},{"@type":"NRID","@value":"9000258219195"},{"@type":"NRID","@value":"9000257700534"},{"@type":"NRID","@value":"9000327101644"},{"@type":"NRID","@value":"9000253135158"},{"@type":"NRID","@value":"9000258219094"},{"@type":"NRID","@value":"9000259839951"},{"@type":"NRID","@value":"9000259839944"},{"@type":"NRID","@value":"9000256007306"},{"@type":"NRID","@value":"9000256016497"},{"@type":"NRID","@value":"9000256014582"},{"@type":"NRID","@value":"9000000799480"},{"@type":"NRID","@value":"9000001672389"},{"@type":"NRID","@value":"9000391399589"},{"@type":"NRID","@value":"9000399219614"},{"@type":"NRID","@value":"9000255702638"},{"@type":"NRID","@value":"9000256014575"},{"@type":"NRID","@value":"9000256023446"},{"@type":"NRID","@value":"9000283370942"},{"@type":"NRID","@value":"9000257719421"},{"@type":"NRID","@value":"9000257712346"},{"@type":"NRID","@value":"9000305641594"},{"@type":"NRID","@value":"9000413727346"},{"@type":"NRID","@value":"9000255702010"},{"@type":"NRID","@value":"9000257700339"},{"@type":"NRID","@value":"9000257703290"},{"@type":"NRID","@value":"9000256019081"},{"@type":"NRID","@value":"9000345347354"},{"@type":"NRID","@value":"9000255698612"},{"@type":"NRID","@value":"9000256011083"},{"@type":"NRID","@value":"9000256023932"},{"@type":"NRID","@value":"9000258219101"},{"@type":"NRID","@value":"9000253134535"},{"@type":"NRID","@value":"9000410462751"},{"@type":"NRID","@value":"9000255700243"},{"@type":"NRID","@value":"9000283626332"},{"@type":"NRID","@value":"9000258219187"},{"@type":"NRID","@value":"9000257702227"},{"@type":"NRID","@value":"9000256020141"},{"@type":"NRID","@value":"9000258219071"},{"@type":"NRID","@value":"9000258219114"},{"@type":"NRID","@value":"9000256007610"},{"@type":"NRID","@value":"9000256014308"},{"@type":"NRID","@value":"9000256016205"},{"@type":"NRID","@value":"9000256022017"},{"@type":"NRID","@value":"9000257717284"},{"@type":"NRID","@value":"9000021808127"},{"@type":"NRID","@value":"9000412589887"},{"@type":"NRID","@value":"9000255698222"},{"@type":"NRID","@value":"9000255699026"},{"@type":"NRID","@value":"9000258218994"},{"@type":"NRID","@value":"9000257706287"},{"@type":"NRID","@value":"9000256011186"},{"@type":"NRID","@value":"9000283117873"},{"@type":"NRID","@value":"9000021858166"},{"@type":"NRID","@value":"9000345434584"},{"@type":"NRID","@value":"9000293837077"},{"@type":"NRID","@value":"9000255700996"},{"@type":"NRID","@value":"9000283626368"},{"@type":"NRID","@value":"9000258219169"},{"@type":"NRID","@value":"9000256013795"},{"@type":"NRID","@value":"9000256018970"},{"@type":"NRID","@value":"9000257718492"},{"@type":"NRID","@value":"9000283626285"},{"@type":"NRID","@value":"9000283626372"},{"@type":"NRID","@value":"9000258219077"},{"@type":"NRID","@value":"9000258218933"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/handa_makoto"}],"foaf:name":[{"@language":"ja","@value":"半田 真"},{"@language":"en","@value":"HANDA Makoto"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University"},{"@language":"ja","@value":"島根大学大学院総合理工学研究科"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"05251931"},{"@type":"NDL_BIB_ID","@value":"000000021279"},{"@type":"ISSN","@value":"05251931"},{"@type":"LISSN","@value":"05251931"},{"@type":"NCID","@value":"AN00222633"}],"prism:publicationName":[{"@language":"ja","@value":"分析化学"},{"@language":"en","@value":"BUNSEKI KAGAKU"},{"@language":"en","@value":"BUNSEKI KAGAKU"},{"@language":"en","@value":"Bunseki kagaku"},{"@language":"ja","@value":"分析化学"}],"dc:publisher":[{"@language":"en","@value":"The Japan Society for Analytical Chemistry"},{"@language":"ja","@value":"公益社団法人 日本分析化学会"}],"prism:publicationDate":"2017","prism:volume":"66","prism:number":"1","prism:startingPage":"39","prism:endingPage":"48"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/027844021"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I027844021"},{"@id":"https://www.jstage.jst.go.jp/article/bunsekikagaku/66/1/66_39/_pdf"}],"availableAt":"2017","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=black%20polyester%20gloves","dc:title":"black polyester gloves"},{"@id":"https://cir.nii.ac.jp/all?q=disperse%20dye","dc:title":"disperse dye"},{"@id":"https://cir.nii.ac.jp/all?q=liquid%20chromatography/linear%20ion%20trap%20mass%20spectrometry","dc:title":"liquid chromatography/linear ion trap mass spectrometry"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040282256888244480","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"16K05722"},{"@type":"JGN","@value":"JP16K05722"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-16K05722/"}],"notation":[{"@language":"ja","@value":"ルテニウム二核とシアニド金属の配位制御によるワイヤー型分子磁石の開発と展開"},{"@language":"en","@value":"Development of wire-type molecular magnets by control of coordination in combination of ruthenium dimer cyanidometallate units"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1361981468818096768","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Blocks of colour IV: The evidential value of blue and red cotton fibres"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981469887764352","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Discrimination of reactively-dyed cotton fibres with thin layer chromatography and UV 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