Kinetic polymerization behavior of fluorinated monomers for dental use
-
- KADOMA Yoshinori
- Department of Applied Functional Molecules, Division of Biofunctional Molecules, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University
書誌事項
- 公開日
- 2010
- 資源種別
- journal article
- DOI
-
- 10.4012/dmj.2010-054
- 公開者
- 一般社団法人 日本歯科理工学会
この論文をさがす
説明
The kinetic polymerization behavior of 2,2,2-trifluoroethyl methacrylate (TFEMA), 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFIPMA), 2,2,2-trifluoroethyl acrylate (TFEA) and 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) was determined by isothermal differential scanning calorimetry (DSC) and high-performance liquid chromatography (HPLC) in order to improve the properties of fluorinated powder-liquid adhesive resins. Conversion and heat of polymerization were calculated, and the solubility of the homopolymers in common solvents was examined. Comparison of their polymerization reactivity with that of MMA revealed that the overall rate of polymerization initiated by benzoyl peroxide (BPO) decreased in the order TFEA>MMA>TFEMA>HFIPA>HFIPMA. Based on the retention time of the monomer determined by HPLC, the hydrophobicity of the monomers was found to increase in the order MMA<TFEA<TFEMA<HFIPA<HFIPMA. The overall research results suggested that TFEA and HFIPA would be potentially promising candidates for the monomer liquid component of fluorinated powder-liquid adhesive resins.
収録刊行物
-
- Dental Materials Journal
-
Dental Materials Journal 29 (5), 602-608, 2010
一般社団法人 日本歯科理工学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390282679693309568
-
- NII論文ID
- 10026669994
-
- NII書誌ID
- AA10443149
-
- ISSN
- 18811361
- 02874547
-
- PubMed
- 20827030
-
- 本文言語コード
- en
-
- 資料種別
- journal article
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
- KAKEN
- OpenAIRE
-
- 抄録ライセンスフラグ
- 使用不可
