{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282679693309568.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.4012/dmj.2010-054"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/dmj/29/5/29_2010-054/_pdf"}},{"identifier":{"@type":"PMID","@value":"20827030"}},{"identifier":{"@type":"NAID","@value":"10026669994"}},{"identifier":{"@type":"URI","@value":"https://search.jamas.or.jp/link/ui/2011175659"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Kinetic polymerization behavior of fluorinated monomers for dental use"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The kinetic polymerization behavior of 2,2,2-trifluoroethyl methacrylate (TFEMA), 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFIPMA), 2,2,2-trifluoroethyl acrylate (TFEA) and 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) was determined by isothermal differential scanning calorimetry (DSC) and high-performance liquid chromatography (HPLC) in order to improve the properties of fluorinated powder-liquid adhesive resins. Conversion and heat of polymerization were calculated, and the solubility of the homopolymers in common solvents was examined. Comparison of their polymerization reactivity with that of MMA revealed that the overall rate of polymerization initiated by benzoyl peroxide (BPO) decreased in the order TFEA>MMA>TFEMA>HFIPA>HFIPMA. Based on the retention time of the monomer determined by HPLC, the hydrophobicity of the monomers was found to increase in the order MMA<TFEA<TFEMA<HFIPA<HFIPMA. The overall research results suggested that TFEA and HFIPA would be potentially promising candidates for the monomer liquid component of fluorinated powder-liquid adhesive resins."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1030003658315413120","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"00092403"},{"@type":"NRID","@value":"1000000092403"},{"@type":"NRID","@value":"9000391829950"},{"@type":"NRID","@value":"9000254397780"},{"@type":"NRID","@value":"9000004579835"},{"@type":"NRID","@value":"9000383708314"},{"@type":"NRID","@value":"9000391828509"},{"@type":"NRID","@value":"9000272965157"},{"@type":"NRID","@value":"9000383708455"},{"@type":"NRID","@value":"9000391827047"},{"@type":"NRID","@value":"9000391823954"},{"@type":"NRID","@value":"9000391820628"},{"@type":"NRID","@value":"9000391817390"},{"@type":"NRID","@value":"9000253649967"},{"@type":"NRID","@value":"9000283427822"},{"@type":"NRID","@value":"9000255861579"},{"@type":"NRID","@value":"9000258545487"},{"@type":"NRID","@value":"9000020021206"},{"@type":"NRID","@value":"9000021164812"},{"@type":"NRID","@value":"9000391827085"},{"@type":"NRID","@value":"9000391817830"},{"@type":"NRID","@value":"9000391826954"},{"@type":"NRID","@value":"9000391823525"},{"@type":"NRID","@value":"9000391829099"},{"@type":"NRID","@value":"9000391818169"},{"@type":"NRID","@value":"9000254397366"},{"@type":"NRID","@value":"9000020054024"},{"@type":"NRID","@value":"9000391826054"},{"@type":"NRID","@value":"9000391817090"},{"@type":"NRID","@value":"9000391822613"},{"@type":"NRID","@value":"9000283426569"},{"@type":"NRID","@value":"9000391823791"},{"@type":"NRID","@value":"9000391823953"},{"@type":"NRID","@value":"9000391825677"},{"@type":"NRID","@value":"9000391818241"},{"@type":"NRID","@value":"9000254397218"},{"@type":"NRID","@value":"9000017484105"},{"@type":"NRID","@value":"9000021143641"},{"@type":"NRID","@value":"9000283425999"},{"@type":"NRID","@value":"9000014420583"},{"@type":"NRID","@value":"9000020113815"},{"@type":"NRID","@value":"9000272965171"},{"@type":"NRID","@value":"9000021792667"},{"@type":"NRID","@value":"9000391820734"},{"@type":"NRID","@value":"9000391823596"},{"@type":"NRID","@value":"9000391826793"},{"@type":"NRID","@value":"9000254421007"},{"@type":"NRID","@value":"9000254929219"},{"@type":"NRID","@value":"9000021230365"},{"@type":"NRID","@value":"9000256428280"},{"@type":"NRID","@value":"9000020761826"},{"@type":"NRID","@value":"9000383708311"},{"@type":"NRID","@value":"9000019244310"},{"@type":"NRID","@value":"9000391826219"},{"@type":"NRID","@value":"9000391829623"},{"@type":"NRID","@value":"9000272965167"},{"@type":"NRID","@value":"9000021793044"},{"@type":"NRID","@value":"9000391816682"},{"@type":"NRID","@value":"9000391822797"},{"@type":"NRID","@value":"9000256045777"},{"@type":"NRID","@value":"9000256542599"},{"@type":"NRID","@value":"9000383707440"},{"@type":"NRID","@value":"9000254396720"},{"@type":"NRID","@value":"9000021768592"},{"@type":"NRID","@value":"9000256427601"},{"@type":"NRID","@value":"9000283426406"},{"@type":"NRID","@value":"9000272965165"},{"@type":"NRID","@value":"9000310465821"},{"@type":"NRID","@value":"9000391827055"},{"@type":"NRID","@value":"9000391817057"},{"@type":"NRID","@value":"9000254396497"},{"@type":"NRID","@value":"9000258546305"},{"@type":"NRID","@value":"9000017038864"},{"@type":"NRID","@value":"9000021147043"},{"@type":"NRID","@value":"9000021694726"},{"@type":"NRID","@value":"9000021677263"},{"@type":"NRID","@value":"9000391829537"},{"@type":"NRID","@value":"9000391828213"},{"@type":"NRID","@value":"9000255827908"},{"@type":"NRID","@value":"9000254930898"},{"@type":"NRID","@value":"9000364616114"},{"@type":"NRID","@value":"9000364616284"},{"@type":"NRID","@value":"9000364616142"},{"@type":"NRID","@value":"9000364616281"}],"foaf:name":[{"@language":"en","@value":"KADOMA Yoshinori"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Applied Functional Molecules, Division of Biofunctional Molecules, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"02874547"},{"@type":"LISSN","@value":"02874547"},{"@type":"EISSN","@value":"18811361"},{"@type":"NCID","@value":"AA10443149"}],"prism:publicationName":[{"@language":"en","@value":"Dental Materials Journal"},{"@language":"en","@value":"Dent. Mater. J."},{"@language":"en","@value":"Dental Materials Journal"}],"dc:publisher":[{"@language":"en","@value":"The Japanese Society for Dental Materials and Devices"},{"@language":"ja","@value":"一般社団法人　日本歯科理工学会"}],"prism:publicationDate":"2010","prism:volume":"29","prism:number":"5","prism:startingPage":"602","prism:endingPage":"608"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"https://www.jstage.jst.go.jp/article/dmj/29/5/29_2010-054/_pdf"},{"@id":"https://search.jamas.or.jp/link/ui/2011175659"}],"availableAt":"2010","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Polymerization%20kinetics","dc:title":"Polymerization kinetics"},{"@id":"https://cir.nii.ac.jp/all?q=Fluorinated%20monomer","dc:title":"Fluorinated monomer"},{"@id":"https://cir.nii.ac.jp/all?q=Differential%20scanning%20calorimetry","dc:title":"Differential scanning calorimetry"}],"project":[{"@id":"https://cir.nii.ac.jp/crid/1040282257028108800","@type":"Project","projectIdentifier":[{"@type":"KAKEN","@value":"20592296"},{"@type":"JGN","@value":"JP20592296"},{"@type":"URI","@value":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20592296/"}],"notation":[{"@language":"ja","@value":"ナノ分子凝集構造制御による軟質レジン接着システムの開発"},{"@language":"en","@value":"Development of soft resin-based adhesion systems with nanomolecular aggregation"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011144455461248","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Mechanical Properties of Poly(alkyl a-fluoroacrylate)s as Denture-base Materials"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574094653534720","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Kinetic evaluation of reactivity of bisphenol A derivatives as radical scavengers for methacrylate polymerization"}]},{"@id":"https://cir.nii.ac.jp/crid/1360855569167681536","@type":"Article","relationType":["references","cites"],"jpcoar:relatedTitle":[{"@value":"Heats of polymeric reactions. 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