{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282680098593792.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/nikkashi1898.69.4_766"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/nikkashi1898/69/4/69_4_766/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004097056"}}],"dc:title":[{"@language":"en","@value":"Synthesis and Reaction of Polyethylenimine Containing Dithiocarbamoyl Group"},{"@value":"ジチオカーバメート基を含むポリエチレンイミンの合成と反応"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@value":"ポリエチレンイミンと水酸化ナトリウム,二硫化炭素の反応で40%以下の-CS-SNa基を含む水溶性のポリマー(CE)をえた。CEは各種の金属イオンにより不溶化されるが,紫外スペクトルなどから,Zn<SUP>2+</SUP>の場合の結合様式としてSおよびNが関与した架橋構造を推定した。CEは塩化ベンジル,モノクロル酢酸エチル,臭化ブチルと反応し-CS-S-R基を含むポリマー(CER)となる。CERは,ジチオカーバメート基が紫外線によりラジカル分解し,遊離ラジカルを生成するので,スチレン,メチルメタクリレート類を光グラフトし,また,そのフィルムは光照射により架橋不溶化し感光性樹脂としての性質を示す。エチレンイミンと水酸化ナトリウム,二硫化炭素の反応では白色のポリマーを与えるが,その生成についてジチオカーバメート化,脱硫,および開環重合を含む反応機構を推定した。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410009221947851139","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000255824525"}],"foaf:name":[{"@language":"en","@value":"OKAWARA Makoto"},{"@language":"ja","@value":"大河原 信"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"東京工業大学資源 化学研究所"}]},{"@id":"https://cir.nii.ac.jp/crid/1410009221947851138","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000255824526"}],"foaf:name":[{"@language":"en","@value":"ORI Masaru"},{"@language":"ja","@value":"織 勝"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"荒川林産化学工業株式会社"}]},{"@id":"https://cir.nii.ac.jp/crid/1030003658348403585","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"90016717"},{"@type":"NRID","@value":"1000090016717"},{"@type":"NRID","@value":"9000256044041"},{"@type":"NRID","@value":"9000021037172"},{"@type":"NRID","@value":"9000253202320"},{"@type":"NRID","@value":"9000010587285"},{"@type":"NRID","@value":"9000021007297"},{"@type":"NRID","@value":"9000020565125"},{"@type":"NRID","@value":"9000255824568"},{"@type":"NRID","@value":"9000003590759"},{"@type":"NRID","@value":"9000256036529"},{"@type":"NRID","@value":"9000007291190"},{"@type":"NRID","@value":"9000021011350"},{"@type":"NRID","@value":"9000006668884"},{"@type":"NRID","@value":"9000391614541"},{"@type":"NRID","@value":"9000256414387"},{"@type":"NRID","@value":"9000020978788"},{"@type":"NRID","@value":"9000020947514"},{"@type":"NRID","@value":"9000255824527"},{"@type":"NRID","@value":"9000004357734"},{"@type":"NRID","@value":"9000006789463"},{"@type":"NRID","@value":"9000000791617"},{"@type":"NRID","@value":"9000347547413"},{"@type":"NRID","@value":"9000258601725"},{"@type":"NRID","@value":"9000020964756"},{"@type":"NRID","@value":"9000021435530"},{"@type":"NRID","@value":"9000021036668"},{"@type":"NRID","@value":"9000256413202"},{"@type":"NRID","@value":"9000258601728"},{"@type":"NRID","@value":"9000021037129"},{"@type":"NRID","@value":"9000002963085"},{"@type":"NRID","@value":"9000007287505"},{"@type":"NRID","@value":"9000020964508"},{"@type":"NRID","@value":"9000020997389"},{"@type":"NRID","@value":"9000326638498"}],"foaf:name":[{"@language":"en","@value":"NAKAI Takeshi"},{"@language":"ja","@value":"中井 武"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"東京工業大学資源 化学研究所"}]},{"@id":"https://cir.nii.ac.jp/crid/1410009221947851136","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000255824528"}],"foaf:name":[{"@language":"en","@value":"IMOTO Eiji"},{"@language":"ja","@value":"井本 英二"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"大阪府立大学工学部"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00232734"},{"@type":"EISSN","@value":"21850860"}],"prism:publicationName":[{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"},{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"}],"prism:publicationDate":"1966","prism:volume":"69","prism:number":"4","prism:startingPage":"766","prism:endingPage":"771"},"reviewed":"false","url":[{"@id":"https://www.jstage.jst.go.jp/article/nikkashi1898/69/4/69_4_766/_pdf"}],"availableAt":"1966","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Medicine","dc:title":"General Medicine"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360283694076825216","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Sulfur-containing Polymers. 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