{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282680098967552.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/nikkashi1898.74.83"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"8200210"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/8200210"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I8200210"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/nikkashi1898/74/1/74_1_83/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004279291"}}],"dc:title":[{"@language":"en","@value":"Syntheses of 2-Chloro- and 2-Amino-o-phenanthroline and Their Condensation"},{"@value":"2-クロルおよび2-アミノ-o-フェナントロリンの合成とその縮合"},{"@language":"ja-Kana","@value":"2-クロル オヨビ 2-アミノ-0-フェナントロリン ノ ゴウセイ ト ソノ シュクゴウ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@value":"2-クロル-o-フェナントロリン (VI) をo-フェナントロリンにジメチル硫酸を反応させて得られるメトサルフェイトの酸化, ならびに五塩化リン処理により好収率で合成することができた。VIをさらにフェノールとアセトアミドの混合溶媒中でアンモニアと反応させ, 2-アミノ-o-フェナントロリン (VII) を得た。mp 187～190℃ 。これら二つの o-フェナントロリン誘導体を酸化バリウムを酸受容体として縮合させ, イミノ型縮合物のジ-(2-o-フェナントロリル)アミン (VIII) を得た。<BR>VII および VIII の紫外スペクトルを測定し,かなりの差異を認めたが, VII のカチオンと VIII のカチオンの紫外スペクトルは互に近似している。また NMR の測定によりVIIIの立体配置を推定した。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1030285133291865984","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20013196"},{"@type":"NRID","@value":"1000020013196"},{"@type":"NRID","@value":"9000006627374"},{"@type":"NRID","@value":"9000004736200"},{"@type":"NRID","@value":"9000016916048"},{"@type":"NRID","@value":"9000258328742"},{"@type":"NRID","@value":"9000254874456"},{"@type":"NRID","@value":"9000256421112"},{"@type":"NRID","@value":"9000256421287"},{"@type":"NRID","@value":"9000254437438"},{"@type":"NRID","@value":"9000007129140"},{"@type":"NRID","@value":"9000258328648"},{"@type":"NRID","@value":"9000021050977"},{"@type":"NRID","@value":"9000021051484"}],"foaf:name":[{"@language":"en","@value":"OGAWA Shojiro"},{"@language":"ja","@value":"小川 昭二郎"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"東京大学生産技術研究所"}]},{"@id":"https://cir.nii.ac.jp/crid/1410853646812742657","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256421113"}],"foaf:name":[{"@language":"en","@value":"GOTOH Nobuyuki"},{"@language":"ja","@value":"後藤 信行"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"東京大学生産技術研究所"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00232734"},{"@type":"EISSN","@value":"21850860"},{"@type":"NDL_BIB_ID","@value":"000000007550"},{"@type":"ISSN","@value":"00232734"},{"@type":"LISSN","@value":"00232734"},{"@type":"NCID","@value":"AN00080721"}],"prism:publicationName":[{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"},{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"}],"prism:publicationDate":"1971","prism:volume":"74","prism:number":"1","prism:startingPage":"83","prism:endingPage":"86"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/8200210"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I8200210"},{"@id":"https://www.jstage.jst.go.jp/article/nikkashi1898/74/1/74_1_83/_pdf"}],"availableAt":"1971","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Medicine","dc:title":"General Medicine"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360565169056819456","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Synthesis of 2,9-Dichloro-1,10-phenanthroline from <i>N</i>,<i>N</i>′-Annelated Phenanthrolinediones"}]},{"@id":"https://cir.nii.ac.jp/crid/1360565169056948608","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@value":"Electronic Spectra of Phenanthrolinediones, Phenanthrolinones, Bipyridinediones, and Amino-Substituted Phenanthrolines"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0032598751"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I8200210"},{"@type":"CROSSREF","@value":"10.1246/nikkashi1898.74.83"},{"@type":"CIA","@value":"130004279291"},{"@type":"CROSSREF","@value":"10.1246/bcsj.64.1821_references_DOI_T2SChP6noXom5OBpGlVx10BSAdC"},{"@type":"CROSSREF","@value":"10.1246/bcsj.63.2710_references_DOI_T2SChP6noXom5OBpGlVx10BSAdC"}]}