{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282680105359232.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/nikkashi1898.61.1043"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/nikkashi1898/61/8/61_8_1043/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004274117"}}],"dc:title":[{"@language":"en","@value":"Trans-joint Reaction of Phenolic Mannich Bases with Some Organic Compounds"},{"@value":"フェノール系マンニッヒ塩基と二,三の化合物との交換連結反応"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@value":"(1)2置換フェノール系マンニッヒ塩基とアセトフェノンとの反応において,トリブロムフェノール添加の効果を見た。その結果反応温度120℃,160℃では効果を示したが,202℃では効果なく添加しない場合よりも生成物の収率が悪い。(2)2置換フェノールマンニツヒ塩基と活性化メチレン化合物,マレイン酸ジエチルエステル,アセト酢酸エチルエステルとの交換連結反応を行い, それぞれ予期される生成物をえた。またアニリン,ο-トルイジン, およびピペリジン等のアミン類との交換連結反応をも行った。(3)1置換フェノールマンニッヒ塩基とアセトフェノンとの反応の場合マンニッヒ塩基同志の反応による樹脂化よりもアセトフェノンとの交換連結の方が起り易いことを認めた。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410009221749607552","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256408418"}],"foaf:name":[{"@language":"en","@value":"Azuma Keiichi"},{"@language":"ja","@value":"東 敬一"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"大阪府立大学工学部"}]},{"@id":"https://cir.nii.ac.jp/crid/1410009221749607553","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256408419"}],"foaf:name":[{"@language":"en","@value":"Imoto Eiji"},{"@language":"ja","@value":"井本 英二"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"大阪府立大学工学部"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00232734"},{"@type":"EISSN","@value":"21850860"}],"prism:publicationName":[{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"},{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"}],"prism:publicationDate":"1958","prism:volume":"61","prism:number":"8","prism:startingPage":"1043","prism:endingPage":"1046"},"reviewed":"false","url":[{"@id":"https://www.jstage.jst.go.jp/article/nikkashi1898/61/8/61_8_1043/_pdf"}],"availableAt":"1958","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Medicine","dc:title":"General Medicine"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1390001206259101056","@type":"Article","relationType":["isReferencedBy"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"亜鉛めっき鋼板上に形成されたマンニッヒ変性フェノール樹脂皮膜の腐食抑制効果に関する電気化学的考察"},{"@language":"en","@value":"Electrochemical Study on Corrosion Inhibition Effect of Mannich-Modified Phenolic Resin Coating on Galvanized Steel"},{"@language":"ja-Kana","@value":"アエンメッキ コウバン ジョウ ニ ケイセイ サレタ マンニッヒ ヘンセイ フェノール ジュシ ヒマク ノ フショク ヨクセイ コウカ ニ カンスル デンキ カガクテキ コウサツ"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0037976807"},{"@type":"CROSSREF","@value":"10.1246/nikkashi1898.61.1043"},{"@type":"CIA","@value":"130004274117"},{"@type":"CROSSREF","@value":"10.3323/jcorr.64.466_references_DOI_PfaLsSSB6TAAjU0j2F7mZqLP8uv"}]}