{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282680109235840.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/nikkashi1898.72.12_2590"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"8199144"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/8199144"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I8199144"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/nikkashi1898/72/12/72_12_2590/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004278567"}}],"dc:title":[{"@language":"en","@value":"Rate and Mechanism of Preparation of Adipic Acid by Single Stage Oxidation of Cyclohexane"},{"@value":"シクロヘキサンの一段酸化におけるアジピン酸の生成機構"},{"@language":"ja-Kana","@value":"シクロヘキサン ノ イチダン サンカ ニ オケル アジピンサン ノ セイセイ キコウ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@value":"酢酸コバルトおよびコバルトアセチルアセトナート触媒の場合について反応の経時変化を調べた。その結果,酢酸コバルト触媒では,1.5時間の誘導期ののち反応が開始するのに対し,コバルトアセチルアセトナート触媒では誘導期はほとんどなく,最大酸化速度も反応開始直後に認められた。そして反応系中のCo<SUP>3+</SUP>やの濃度が低下すると反応速度も低下した。酢酸コバルト(Co(OAc)<SUB>2</SUB>・4H<SUB>2</SUB>O)触媒を反応前過酢酸で前処理してCo<SUP>3+</SUP>にして仕込むと,誘導期は消滅し,最大酸化速度も反応開始直後に観察され,アジピン酸の選択率も増大することが判った。これらの諸結果から活性な触媒形態はCo<SUP>3+</SUP>に酢酸が配位した状態であると推定された。<BR>本反応の反応次数は,シクロヘキサン,Co<SUP>3+</SUP>の濃度のおのおのに一次で,見掛けの連鎖長はかなり短かいことが判った。これらの結果から本反応は<BR>Co<SUP>3+</SUP>+RH→Co<SUP>2+</SUP>+R・+H<SUP>+</SUP>(RH:シクロヘキサン)<BR>によって反応が開始されることが推定された。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410853646878231042","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256419028"}],"foaf:name":[{"@language":"en","@value":"TANAKA Kyugo"},{"@language":"ja","@value":"田中 久吾"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"旭化成工業(株)化成 品研究室"}]},{"@id":"https://cir.nii.ac.jp/crid/1410853646878231040","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256419029"}],"foaf:name":[{"@language":"en","@value":"HONDA Makoto"},{"@language":"ja","@value":"本多 允"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"旭化成工業(株)化成 品研究室"}]},{"@id":"https://cir.nii.ac.jp/crid/1410853646878231041","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256419030"}],"foaf:name":[{"@language":"en","@value":"INOUE Goro"},{"@language":"ja","@value":"井上 伍郎"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"旭化成工業(株)技術研究所"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00232734"},{"@type":"EISSN","@value":"21850860"},{"@type":"NDL_BIB_ID","@value":"000000007550"},{"@type":"ISSN","@value":"00232734"},{"@type":"LISSN","@value":"00232734"},{"@type":"NCID","@value":"AN00080721"}],"prism:publicationName":[{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"},{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"}],"prism:publicationDate":"1969","prism:volume":"72","prism:number":"12","prism:startingPage":"2590","prism:endingPage":"2593"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/8199144"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I8199144"},{"@id":"https://www.jstage.jst.go.jp/article/nikkashi1898/72/12/72_12_2590/_pdf"}],"availableAt":"1969","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=General%20Medicine","dc:title":"General Medicine"}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0037981869"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I8199144"},{"@type":"CROSSREF","@value":"10.1246/nikkashi1898.72.12_2590"},{"@type":"CIA","@value":"130004278567"}]}