{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282680111547008.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1246/nikkashi1898.63.12_2146"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/nikkashi1898/63/12/63_12_2146/_pdf"}},{"identifier":{"@type":"NAID","@value":"130004274683"}}],"dc:title":[{"@language":"en","@value":"A Synthesis of Organic Carbonates"},{"@value":"炭酸エステルの合成"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@value":"ハロゲン化炭化水素と炭酸カリウムとから炭酸エステルを合成する方法について研究を行ない,ジメチルホルムアミドを溶媒として90～150℃で反応を行なわせることによって好収率で炭酸エステルが得られることを明らかにした。副反応としてアルコール,オレフィンの生成が認められるが,反応系を無水の状態に保つことによって,これらはある程度抑制でぎる。臭化-<I>n</I>-アルキル(C<SUB>3</SUB>H<SUB>7</SUB>Br～C<SUB>12</SUB>H<SUB>25</SUB>Br)からは30～40%の収率で炭酸-<I>n</I>-アルキルを,塩化アリルまたは臭化アリルからは50～70%の収率で炭酸アリルを,塩化べンジル,<I>o</I>-,<I>m</I>-,<I>p</I>-メチル塩化ベンジル,<I>p</I>-クロル塩化ベンジルおよびα-クロルメチルメフタリンからは50～80%の収率で相当する炭酸エステルを合成した。"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410853646746332160","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256409572"}],"foaf:name":[{"@language":"en","@value":"Fukui Ken-ichi"},{"@language":"ja","@value":"福井 謙一"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"京都大学工学部燃料化学教室"}]},{"@id":"https://cir.nii.ac.jp/crid/1410853646746332162","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256409573"}],"foaf:name":[{"@language":"en","@value":"Yoneda Shigeo"},{"@language":"ja","@value":"米田 茂夫"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"京都大学工学部燃料化学教室"}]},{"@id":"https://cir.nii.ac.jp/crid/1410853646746332163","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256409574"}],"foaf:name":[{"@language":"en","@value":"Takayama Hideo"},{"@language":"ja","@value":"高山 秀男"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"京都大学工学部燃料化学教室"}]},{"@id":"https://cir.nii.ac.jp/crid/1410009221815858817","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000256403995"}],"foaf:name":[{"@language":"en","@value":"Kitano Hisao"},{"@language":"ja","@value":"北野 尚男"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"京都大学工学部燃料化学教室"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00232734"},{"@type":"EISSN","@value":"21850860"}],"prism:publicationName":[{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"},{"@language":"en","@value":"The Journal of the Society of Chemical Industry, Japan"},{"@language":"ja","@value":"工業化学雑誌"}],"dc:publisher":[{"@language":"en","@value":"The Chemical Society of Japan"}],"prism:publicationDate":"1960","prism:volume":"63","prism:number":"12","prism:startingPage":"2146","prism:endingPage":"2148"},"reviewed":"false","url":[{"@id":"https://www.jstage.jst.go.jp/article/nikkashi1898/63/12/63_12_2146/_pdf"}],"availableAt":"1960","dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:0038703475"},{"@type":"CROSSREF","@value":"10.1246/nikkashi1898.63.12_2146"},{"@type":"CIA","@value":"130004274683"}]}