{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282681265310336.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1295/polymj.29.642"}},{"identifier":{"@type":"COI","@value":"1:CAS:528:DyaK2sXlsFClurg%3D"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"4277822"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/4277822"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I4277822"}},{"identifier":{"@type":"NAID","@value":"10006272475"}}],"dc:title":[{"@language":"en","@value":"Morphological Study on Binary Blends of Poly(.EPSILON.-caprolactone)-block-Polybutadiene and Poly(.EPSILON.-caprolactone)."},{"@value":"Morphological Study on Binary Blends of Poly(ε-caprolactone)-block-Polybutadiene and Poly(ε-caprolactone)"},{"@language":"ja-Kana","@value":"Morphological Study on Binary Blends of"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"The morphology and melting behavior of binary blends of poly(ε-caprolactone)-<I>block</I>-polybutadiene (PCL-<I>b</I>-PB) and poly(ε-caprolactone) homopolymer (PCL) were investigated by small-angle X-ray scattering (SAXS) and differential scanning calorimetry (DSC) as a function of the homopolymer fraction φ<SUB>homo</SUB> in the system. Three sets of the blends were prepared considering the degree of miscibility between PCL-<I>b</I>-PB and PCL in the melt. The morphology after crystallization of PCL and the PCL block in PCL-<I>b</I>-PB depended strongly on the miscibility in the melt; when PCL was uniformly dissolved with the PCL block in the microdomain structure of PCL-<I>b</I>-PB, an alternating structure of lamellae and amorphous layers (lamellar morphology) was formed in which the PCL block and PCL together made a lamellar crystal, suggesting the formation of a <I>mixed crystal</I> composed of the PCL block and PCL. When PCL was localized in the microdomain structure or macroscopically segregated in the melt, two separate crystalline regions were observed over a wide range of φ<SUB>homo</SUB>, each consisting of PCL and PCL+PCL-<I>b</I>-PB. The lamellar morphology is qualitatively discussed as a function of φ<SUB>homo</SUB> from the viewpoint of the chain conformation of the PB block."}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1030003658364585856","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"20156194"},{"@type":"NRID","@value":"1000020156194"},{"@type":"NRID","@value":"9000257747607"},{"@type":"NRID","@value":"9000256200786"},{"@type":"NRID","@value":"9000020149245"},{"@type":"NRID","@value":"9000257751157"},{"@type":"NRID","@value":"9000002112812"},{"@type":"NRID","@value":"9000283198133"},{"@type":"NRID","@value":"9000014202000"},{"@type":"NRID","@value":"9000403952589"},{"@type":"NRID","@value":"9000014202011"},{"@type":"NRID","@value":"9000021287055"},{"@type":"NRID","@value":"9000257752847"},{"@type":"NRID","@value":"9000257750208"},{"@type":"NRID","@value":"9000265538799"},{"@type":"NRID","@value":"9000257744879"},{"@type":"NRID","@value":"9000257745708"},{"@type":"NRID","@value":"9000017379003"},{"@type":"NRID","@value":"9000283869190"},{"@type":"NRID","@value":"9000020346293"},{"@type":"NRID","@value":"9000283198995"},{"@type":"NRID","@value":"9000283197633"},{"@type":"NRID","@value":"9000283198741"},{"@type":"NRID","@value":"9000256199383"},{"@type":"NRID","@value":"9000283197629"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0043742"}],"foaf:name":[{"@language":"en","@value":"Nojima Shuichi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST)"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282681265310336","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Sasaki Shintaro"}],"jpcoar:affiliationName":[{"@language":"en","@value":"School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST)"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282681265310337","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000000472657"}],"foaf:name":[{"@language":"en","@value":"Kuroda Masahiro"}],"jpcoar:affiliationName":[{"@language":"en","@value":"School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST)"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00323896"},{"@type":"EISSN","@value":"13490540"},{"@type":"NDL_BIB_ID","@value":"000000128645"},{"@type":"ISSN","@value":"00323896"},{"@type":"LISSN","@value":"00323896"},{"@type":"NCID","@value":"AA00777013"}],"prism:publicationName":[{"@language":"en","@value":"Polymer Journal"},{"@language":"en","@value":"Polym. J."}],"dc:publisher":[{"@language":"en","@value":"The Society of Polymer Science, Japan"}],"prism:publicationDate":"1997","prism:volume":"29","prism:number":"8","prism:startingPage":"642","prism:endingPage":"648"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/4277822"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I4277822"}],"availableAt":"1997","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Diblock%20Copolymer-Homopolymer%20Blend","dc:title":"Diblock Copolymer-Homopolymer Blend"},{"@id":"https://cir.nii.ac.jp/all?q=Crystallization","dc:title":"Crystallization"},{"@id":"https://cir.nii.ac.jp/all?q=Morphology","dc:title":"Morphology"},{"@id":"https://cir.nii.ac.jp/all?q=Small-Angle%20X-Ray%20Scattering","dc:title":"Small-Angle X-Ray Scattering"},{"@id":"https://cir.nii.ac.jp/all?q=Differential%20Scanning%20Calorimetry","dc:title":"Differential Scanning Calorimetry"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360011145305284480","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Crystallization of ε-caprolactone blocks within a crosslinked microdomain structure of poly(ε-caprolactone)-block-polybutadiene"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011145814861184","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Compatibility and crystallization of tetrahydrofuran-methyl methacrylate diblock copolymer/polytetrahydrofuran blends"}]},{"@id":"https://cir.nii.ac.jp/crid/1360011146565716224","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Synchrotron SAXS Study of Crystallization and Microphase Separation in Compatible Mixtures of Tetrahydrofuran−Methyl Methacrylate Diblock Copolymer and Poly(tetrahydrofuran)"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574093651929728","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Amorphous-crystalline block copolymer and amorphous homopolymer blends. 1. 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