{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282681502161920.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1295/koron.2017-0037"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"028675836"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/028675836"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I028675836"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/koron/74/6/74_2017-0037/_pdf"}},{"identifier":{"@type":"NAID","@value":"130006218929"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"ja","@value":"3,4-エチレンジオキシチオフェンとジブロモカルバゾールの直接的アリール化重縮合に関する検討"},{"@language":"en","@value":"Study on Direct Arylation Polycondensation of 3,4-Ethylenedioxythiophene with Dibromocarbazole"},{"@language":"ja-Kana","@value":"3,4-エチレンジオキシチオフェン ト ジブロモカルバゾール ノ チョクセツテキ アリールカジュウ シュクゴウ ニ カンスル ケントウ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"Palladium-catalyzed direct arylation polycondensation of 3,4-ethylenedioxythiophene (EDOT) with dibromocarbazole was investigated by varying heating conditions and microwave heating conditions. The polycondensation of EDOT with 3,6-dibromocarbazole resulted in the alternating copolymer (<i>M</i><sub>n</sub> = 6600) in high yield. In contrast, 2,7-dibromocarbazole shows low reactivity and the polycondensation of EDOT with 2,7-dibromocarbazole resulted in an oligomeric product (<i>M</i><sub>n</sub> < 4000) in low 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正太郎"},{"@language":"en","@value":"HAYASHI Shotaro"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Applied Chemistry, National Defense Academy"},{"@language":"ja","@value":"防衛大学校応用化学科"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282681502161924","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000375884993"}],"foaf:name":[{"@language":"ja","@value":"清水 弘樹"},{"@language":"en","@value":"SHIMIZU Hiroki"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Bioproduction Research Institute, Department of Life Science and Biotechnology, National Institute of Advanced Industrial Science and Technology (AIST)"},{"@language":"ja","@value":"産業技術総合研究所北海道センター生命工学領域生物プロセス研究部門"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282681502161921","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000375884994"}],"foaf:name":[{"@language":"ja","@value":"小島 督央"},{"@language":"en","@value":"KOJIMA Yoshihisa"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Applied Chemistry, National Defense Academy"},{"@language":"ja","@value":"防衛大学校応用化学科"}]},{"@id":"https://cir.nii.ac.jp/crid/1410282681502161923","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000375884995"}],"foaf:name":[{"@language":"ja","@value":"山本 進一"},{"@language":"en","@value":"YAMAMOTO Shin-ichi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Applied Chemistry, National Defense 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俊雄"},{"@language":"en","@value":"KOIZUMI Toshio"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Applied Chemistry, National Defense Academy"},{"@language":"ja","@value":"防衛大学校応用化学科"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"03862186"},{"@type":"LISSN","@value":"03862186"},{"@type":"EISSN","@value":"18815685"},{"@type":"CODEN","@value":"KBRBA"},{"@type":"NDL_BIB_ID","@value":"000000025923"},{"@type":"ISSN","@value":"03862186"},{"@type":"NCID","@value":"AN00085011"}],"prism:publicationName":[{"@language":"en","@value":"KOBUNSHI RONBUNSHU"},{"@language":"ja","@value":"高分子論文集"},{"@language":"en","@value":"KOBUNSHI RONBUNSHU"},{"@language":"ja","@value":"高分子論文集"}],"dc:publisher":[{"@language":"en","@value":"The Society of Polymer Science, Japan"},{"@language":"ja","@value":"公益社団法人 高分子学会"}],"prism:publicationDate":"2017","prism:volume":"74","prism:number":"6","prism:startingPage":"588","prism:endingPage":"593"},"reviewed":"false","url":[{"@id":"http://id.ndl.go.jp/bib/028675836"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I028675836"},{"@id":"https://www.jstage.jst.go.jp/article/koron/74/6/74_2017-0037/_pdf"}],"availableAt":"2017","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Conjugated%20Polymers","dc:title":"Conjugated Polymers"},{"@id":"https://cir.nii.ac.jp/all?q=3,4-Ethylenedioxythiophene","dc:title":"3,4-Ethylenedioxythiophene"},{"@id":"https://cir.nii.ac.jp/all?q=Direct%20Arylation","dc:title":"Direct 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