{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390282763099119232.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.11370/isj.58.122"}},{"identifier":{"@type":"HDL","@value":"https://hdl.handle.net/20.500.14094/90006765"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"029513608"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/029513608"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I029513608"}},{"identifier":{"@type":"NAID","@value":"130007593417"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"ja","@value":"高分子界面の接着特性における元素ブロックの役割"},{"@language":"en","@value":"Element-blocks at Polymer “Interphase” for Adhesion"},{"@language":"ja-Kana","@value":"コウブンシ カイメン ノ セッチャク トクセイ ニ オケル ゲンソ ブロック ノ ヤクワリ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"<p>“Element-block” materials with various groups of elements possess unique optical, electrical and reactive properties. The “element-block” also shows attractive properties at restricted surface and interface. Therefore, the “element-block” is accepted in the field of adhesion including image displays. Herein, we focused the cobalt complex as one of typical “element-block” for surface treatment and investigated the primer effect of adhesion properties in detail. From the various measurements, the spatial interface, namely “interphase”, was observed and the thickness of the interphase defined adhesive strength. In addition, we evaluated the thickness of interphase using various adhesion systems and revealed the relationship between the thickness of interphase and adhesion strength. We clarified the formation mechanism of the interphase region.</p>"},{"@language":"ja","@value":"<p>元素ブロックは，さまざまな元素の特性を活かした光学特性や電気特性·反応特性を持つ原子団であるが，それは表面·界面といった束縛された環境においても同様に，特異な性質を発現する．そのため，接着においても画像表示のディスプレイをはじめとした応用展開が期待できる．本稿では，元素ブロックであるコバルト錯体を表面処理のためのプライマーとした接着機構評価を詳細に紹介した．種々の測定の結果，接着界面が空間的な広がりを持つ“interphase”として存在し，界面厚みが接着強度と強い相関を持つことが明らかとなった．さらに，ポリエチレン (PE) /アイソタクチックポリプロピレン (<i>it. </i>PP) の異種高分子界面，PE/PEの同種高分子界面を取り上げ，共焦点ラマン分光法に加え，走査型サーマル顕微鏡やマイクロビームX線回折といった多様な手法での界面解析での界面厚みの評価と接着性能との関係性についても紹介し，“interphase”が形成される要因について解明した．</p>"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1420282801212102016","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70758078"},{"@type":"NRID","@value":"1000070758078"},{"@type":"ORCID","@value":"0000-0002-7258-5891"},{"@type":"NRID","@value":"9000399839090"},{"@type":"NRID","@value":"9000403042912"},{"@type":"NRID","@value":"9000367858701"},{"@type":"NRID","@value":"9000402819031"},{"@type":"NRID","@value":"9000321618377"},{"@type":"NRID","@value":"9000389445767"},{"@type":"NRID","@value":"9000397707173"},{"@type":"NRID","@value":"9000399345408"},{"@type":"NRID","@value":"9000311070080"},{"@type":"NRID","@value":"9000403042906"},{"@type":"NRID","@value":"9000399166404"},{"@type":"NRID","@value":"9000002924888"},{"@type":"NRID","@value":"9000388537970"},{"@type":"NRID","@value":"9000362202873"},{"@type":"NRID","@value":"9000311505740"},{"@type":"NRID","@value":"9000308732540"},{"@type":"NRID","@value":"9000319071479"},{"@type":"NRID","@value":"9000397426603"},{"@type":"NRID","@value":"9000388537977"},{"@type":"NRID","@value":"9000239878901"},{"@type":"NRID","@value":"9000408576127"},{"@type":"NRID","@value":"9000390430259"},{"@type":"NRID","@value":"9000381457541"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/7000011892"}],"foaf:name":[{"@language":"ja","@value":"松本 拓也"},{"@language":"en","@value":"MATSUMOTO Takuya"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Graduate School of Engineering, Kobe University"},{"@language":"ja","@value":"神戸大学大学院　工学研究科"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751139211008","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"40180624"},{"@type":"NRID","@value":"1000040180624"},{"@type":"NRID","@value":"9000389445792"},{"@type":"NRID","@value":"9000399839095"},{"@type":"NRID","@value":"9000403042913"},{"@type":"NRID","@value":"9000351085229"},{"@type":"NRID","@value":"9000367858702"},{"@type":"NRID","@value":"9000402819032"},{"@type":"NRID","@value":"9000273005999"},{"@type":"NRID","@value":"9000389445772"},{"@type":"NRID","@value":"9000397707176"},{"@type":"NRID","@value":"9000364998526"},{"@type":"NRID","@value":"9000399345409"},{"@type":"NRID","@value":"9000006187465"},{"@type":"NRID","@value":"9000397426542"},{"@type":"NRID","@value":"9000238257185"},{"@type":"NRID","@value":"9000403042908"},{"@type":"NRID","@value":"9000239595981"},{"@type":"NRID","@value":"9000399166405"},{"@type":"NRID","@value":"9000000886830"},{"@type":"NRID","@value":"9000388537971"},{"@type":"NRID","@value":"9000018822287"},{"@type":"NRID","@value":"9000356653102"},{"@type":"NRID","@value":"9000362202879"},{"@type":"NRID","@value":"9000258301144"},{"@type":"NRID","@value":"9000404850446"},{"@type":"NRID","@value":"9000397426604"},{"@type":"NRID","@value":"9000356891775"},{"@type":"NRID","@value":"9000256896387"},{"@type":"NRID","@value":"9000002058679"},{"@type":"NRID","@value":"9000388537982"},{"@type":"NRID","@value":"9000304690764"},{"@type":"NRID","@value":"9000390430260"},{"@type":"NRID","@value":"9000301713739"},{"@type":"NRID","@value":"9000389445806"},{"@type":"NRID","@value":"9000010674849"},{"@type":"NRID","@value":"9000018656703"},{"@type":"NRID","@value":"9000239609727"},{"@type":"NRID","@value":"9000388537976"},{"@type":"NRID","@value":"9000402817400"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0015046"}],"foaf:name":[{"@language":"ja","@value":"西野 孝"},{"@language":"en","@value":"NISHINO Takashi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Graduate School of Engineering, Kobe University"},{"@language":"ja","@value":"神戸大学大学院　工学研究科"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"13444425"},{"@type":"EISSN","@value":"18804675"},{"@type":"NDL_BIB_ID","@value":"000000104383"},{"@type":"ISSN","@value":"13444425"},{"@type":"LISSN","@value":"13444425"},{"@type":"NCID","@value":"AA1137305X"}],"prism:publicationName":[{"@language":"ja","@value":"日本画像学会誌"},{"@language":"en","@value":"NIHON GAZO GAKKAISHI (Journal of the Imaging Society of Japan)"},{"@language":"en","@value":"NIHON GAZO GAKKAISHI"},{"@language":"en","@value":"Journal of the Imaging Society of Japan"},{"@language":"ja","@value":"日本画像学会誌"}],"dc:publisher":[{"@language":"en","@value":"The Imaging Society of Japan"},{"@language":"ja","@value":"一般社団法人 日本画像学会"}],"prism:publicationDate":"2019-02-10","prism:volume":"58","prism:number":"1","prism:startingPage":"122","prism:endingPage":"130"},"dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/029513608"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I029513608"},{"@id":"http://www.lib.kobe-u.ac.jp/handle_kernel/90006765"}],"availableAt":"2019-02-10","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Adhesion","dc:title":"Adhesion"},{"@id":"https://cir.nii.ac.jp/all?q=Interphase","dc:title":"Interphase"},{"@id":"https://cir.nii.ac.jp/all?q=Raman%20scattering","dc:title":"Raman scattering"},{"@id":"https://cir.nii.ac.jp/all?q=%3Ci%3EIsotactic%20%3C/i%3Epolypropylene","dc:title":"<i>Isotactic </i>polypropylene"},{"@id":"https://cir.nii.ac.jp/all?q=Primer","dc:title":"Primer"},{"@id":"https://cir.nii.ac.jp/all?q=%E6%8E%A5%E7%9D%80","dc:title":"接着"},{"@id":"https://cir.nii.ac.jp/all?q=%E4%B8%89%E6%AC%A1%E5%85%83%E7%95%8C%E9%9D%A2","dc:title":"三次元界面"},{"@id":"https://cir.nii.ac.jp/all?q=%E3%83%A9%E3%83%9E%E3%83%B3%E6%95%A3%E4%B9%B1","dc:title":"ラマン散乱"},{"@id":"https://cir.nii.ac.jp/all?q=%E3%82%A2%E3%82%A4%E3%82%BD%E3%82%BF%E3%82%AF%E3%83%81%E3%83%83%E3%82%AF%E3%83%9D%E3%83%AA%E3%83%97%E3%83%AD%E3%83%94%E3%83%AC%E3%83%B3","dc:title":"アイソタクチックポリプロピレン"},{"@id":"https://cir.nii.ac.jp/all?q=%E3%83%97%E3%83%A9%E3%82%A4%E3%83%9E%E3%83%BC","dc:title":"プライマー"}],"dcterms:subject":[{"subjectScheme":"Other","notation":[{"@language":"ja","@value":"接着"}]},{"subjectScheme":"Other","notation":[{"@language":"ja","@value":"三次元界面"}]},{"subjectScheme":"Other","notation":[{"@language":"ja","@value":"ラマン散乱"}]},{"subjectScheme":"Other","notation":[{"@language":"ja","@value":"アイソタクチックポリプロピレン"}]},{"subjectScheme":"Other","notation":[{"@language":"ja","@value":"プライマー"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Adhesion"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Interphase"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Raman scattering"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Isotactic polypropylene"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Primer"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:2007085812"},{"@type":"IRDB","@value":"oai:irdb.nii.ac.jp:01257:0005617299"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I029513608"},{"@type":"CIA","@value":"130007593417"}]}