{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390295603316204800.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.2355/tetsutohagane.tetsu-2022-110"}},{"identifier":{"@type":"HDL","@value":"https://hdl.handle.net/2324/7172653"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"032796242"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/032796242"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I032796242"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/tetsutohagane/109/4/109_TETSU-2022-110/_pdf"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Corrosion Resistance of Zn-Ni Alloy Films Electroplated from Alkaline Zincate Solution Containing Brightener"},{"@language":"ja","@value":"光沢剤を含むアルカリジンケート浴から電析したZn-Ni合金皮膜の耐食性"},{"@language":"ja-Kana","@value":"コウタクザイ オ フクム アルカリジンケートヨク カラ デンセキシタ Zn-Ni ゴウキン ヒマク ノ タイショクセイ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"<p>Zn–Ni alloys were electroplated on an Fe plate with thicknesses of 40 μm at 500 A·m<sup>−2</sup> and 293 K in unagitated zincate solutions. The reaction product of epichlorohydrin and imidazole (IME) was added in the solution as a brightener at the concentration of 0-5 ml/dm<sup>−3</sup>. The corrosion resistance of the obtained Zn–Ni alloys films was investigated from the polarization curve in 3 mass% NaCl solution before and after the corrosion treatment (formation of corrosion products) in NaCl solution for 48 h. Before the corrosion treatment, the corrosion current density of plated films rarely changed regardless of addition of IME into the zincate solution because the reduction reaction of dissolved oxygen rarely changed. However, in films plated from the solution containing IME, the anode reaction was suppressed and the corrosion potential shifted to noble direction. The suppression of anode reaction with an addition of IME in plating solution is attributed to the increase in γ-phase in plated films. On the other hand, after the corrosion treatment, the morphology of Zn chloride hydroxide of corrosion product was uniformly formed on the surface with increasing the concentration of IME. The reduction reaction of dissolved oxygen was suppressed with increasing the concentration of IME, resulting in decrease in corrosion current density.</p>"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410295603316204800","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Bae Sung Hwa"},{"@language":"ja","@value":"裵 聖和"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Graduate School of Engineering, Kyushu University"},{"@language":"ja","@value":"九州大学大学院工学府"}]},{"@id":"https://cir.nii.ac.jp/crid/1410295603316204803","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Oue Satoshi"},{"@language":"ja","@value":"大上 悟"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"九州大学大学院工学研究院"},{"@language":"en","@value":"Faculty of Engineering, Kyushu 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Yu-ki"},{"@language":"ja","@value":"谷ノ内 勇樹"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Faculty of Engineering, Kyushu University"},{"@language":"ja","@value":"九州大学大学院工学研究院"}]},{"@id":"https://cir.nii.ac.jp/crid/1410295603316204801","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Son Injoon"},{"@language":"ja","@value":"孫 仁俊"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Materials Science and Metallurgy, Kyungpook National University"},{"@language":"ja","@value":"慶北大学工科大学"}]},{"@id":"https://cir.nii.ac.jp/crid/1420564276188232960","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70325504"},{"@type":"NRID","@value":"1000070325504"},{"@type":"ORCID","@value":"0000-0002-7815-446X"},{"@type":"NRID","@value":"9000258738936"},{"@type":"NRID","@value":"9000286621217"},{"@type":"NRID","@value":"9000404514312"},{"@type":"NRID","@value":"9000257845523"},{"@type":"NRID","@value":"9000259835739"},{"@type":"NRID","@value":"9000001133226"},{"@type":"NRID","@value":"9000242079618"},{"@type":"NRID","@value":"9000240080912"},{"@type":"NRID","@value":"9000257852631"},{"@type":"NRID","@value":"9000257851543"},{"@type":"NRID","@value":"9000359878763"},{"@type":"NRID","@value":"9000367053920"},{"@type":"NRID","@value":"9000257845375"},{"@type":"NRID","@value":"9000314065090"},{"@type":"NRID","@value":"9000327926068"},{"@type":"NRID","@value":"9000329013731"},{"@type":"NRID","@value":"9000399499244"},{"@type":"NRID","@value":"9000257848381"},{"@type":"NRID","@value":"9000263062719"},{"@type":"NRID","@value":"9000408906736"},{"@type":"NRID","@value":"9000369342779"},{"@type":"NRID","@value":"9000299559121"},{"@type":"NRID","@value":"9000286634281"},{"@type":"NRID","@value":"9000415080425"},{"@type":"NRID","@value":"9000257851022"},{"@type":"NRID","@value":"9000261023599"},{"@type":"NRID","@value":"9000399226900"},{"@type":"NRID","@value":"9000240536620"},{"@type":"NRID","@value":"9000001404225"},{"@type":"NRID","@value":"9000369745932"},{"@type":"NRID","@value":"9000305637742"},{"@type":"NRID","@value":"9000253262761"},{"@type":"NRID","@value":"9000398825573"},{"@type":"NRID","@value":"9000391399113"},{"@type":"NRID","@value":"9000398985007"},{"@type":"NRID","@value":"9000265249151"},{"@type":"NRID","@value":"9000391399348"},{"@type":"NRID","@value":"9000361295960"},{"@type":"NRID","@value":"9000292181518"},{"@type":"NRID","@value":"9000257848519"},{"@type":"NRID","@value":"9000401428570"},{"@type":"NRID","@value":"9000326263504"},{"@type":"NRID","@value":"9000405872138"},{"@type":"NRID","@value":"9000406373827"},{"@type":"NRID","@value":"9000257846256"},{"@type":"NRID","@value":"9000259835735"},{"@type":"NRID","@value":"9000242732809"},{"@type":"NRID","@value":"9000345257359"},{"@type":"NRID","@value":"9000356581517"},{"@type":"NRID","@value":"9000020937012"},{"@type":"NRID","@value":"9000410514056"},{"@type":"NRID","@value":"9000314065109"},{"@type":"NRID","@value":"9000242079622"},{"@type":"NRID","@value":"9000412211065"},{"@type":"NRID","@value":"9000410269096"},{"@type":"NRID","@value":"9000399379922"},{"@type":"NRID","@value":"9000411824551"},{"@type":"NRID","@value":"9000257842189"},{"@type":"NRID","@value":"9000404317894"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/read0162884"}],"foaf:name":[{"@language":"en","@value":"Nakano Hiroaki"},{"@language":"ja","@value":"中野 博昭"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"九州大学大学院工学研究院"},{"@language":"en","@value":"Faculty of Engineering, Kyushu University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00211575"},{"@type":"LISSN","@value":"00211575"},{"@type":"EISSN","@value":"18832954"},{"@type":"NDL_BIB_ID","@value":"000000015659"},{"@type":"ISSN","@value":"00211575"},{"@type":"NCID","@value":"AN00151251"}],"prism:publicationName":[{"@language":"en","@value":"Tetsu-to-Hagane"},{"@language":"ja","@value":"鉄と鋼"},{"@language":"en","@value":"Tetsu-to-Hagane"},{"@language":"en","@value":"Journal of the Iron and Steel Institute of Japan"},{"@language":"ja","@value":"鉄と鋼"}],"dc:publisher":[{"@language":"en","@value":"The Iron and Steel Institute of Japan"},{"@language":"ja","@value":"一般社団法人 日本鉄鋼協会"}],"prism:publicationDate":"2023","prism:volume":"109","prism:number":"4","prism:startingPage":"289","prism:endingPage":"300"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/032796242"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I032796242"},{"@id":"https://www.jstage.jst.go.jp/article/tetsutohagane/109/4/109_TETSU-2022-110/_pdf"}],"availableAt":"2023","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=electroplating","dc:title":"electroplating"},{"@id":"https://cir.nii.ac.jp/all?q=zinc-nickel%20alloy","dc:title":"zinc-nickel alloy"},{"@id":"https://cir.nii.ac.jp/all?q=corrosion","dc:title":"corrosion"},{"@id":"https://cir.nii.ac.jp/all?q=corrosion%20current%20density","dc:title":"corrosion current density"},{"@id":"https://cir.nii.ac.jp/all?q=corrosion%20potential","dc:title":"corrosion potential"},{"@id":"https://cir.nii.ac.jp/all?q=corrosion%20product","dc:title":"corrosion product"},{"@id":"https://cir.nii.ac.jp/all?q=polarization%20curve","dc:title":"polarization curve"},{"@id":"https://cir.nii.ac.jp/all?q=brightener","dc:title":"brightener"},{"@id":"https://cir.nii.ac.jp/all?q=zincate%20solution","dc:title":"zincate solution"},{"@id":"https://cir.nii.ac.jp/all?q=zincate","dc:title":"zincate"},{"@id":"https://cir.nii.ac.jp/all?q=electroplating","dc:title":"electroplating"},{"@id":"https://cir.nii.ac.jp/all?q=zinc-nickel%20alloy","dc:title":"zinc-nickel alloy"},{"@id":"https://cir.nii.ac.jp/all?q=corrosion","dc:title":"corrosion"},{"@id":"https://cir.nii.ac.jp/all?q=corrosion%20current%20density","dc:title":"corrosion current density"},{"@id":"https://cir.nii.ac.jp/all?q=corrosion%20potential","dc:title":"corrosion potential"},{"@id":"https://cir.nii.ac.jp/all?q=corrosion%20product","dc:title":"corrosion product"},{"@id":"https://cir.nii.ac.jp/all?q=polarization%20curve","dc:title":"polarization curve"},{"@id":"https://cir.nii.ac.jp/all?q=brightener","dc:title":"brightener"},{"@id":"https://cir.nii.ac.jp/all?q=zincate%20solution","dc:title":"zincate solution"},{"@id":"https://cir.nii.ac.jp/all?q=zincate","dc:title":"zincate"}],"dcterms:subject":[{"subjectScheme":"Other","notation":[{"@language":"en","@value":"electroplating"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"zinc-nickel alloy"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"corrosion"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"corrosion current density"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"corrosion potential"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"corrosion product"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"polarization curve"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"brightener"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"zincate solution"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"zincate"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360016866527477120","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Role of the newly synthesized brightener in modification of surface properties of Zn-Ni alloy electrodeposited on steel substrate"}]},{"@id":"https://cir.nii.ac.jp/crid/1360016868508726400","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electrochemical behaviour and analysis of Zn and Zn–Ni alloy anti-corrosive coatings deposited from citrate baths"}]},{"@id":"https://cir.nii.ac.jp/crid/1360298341034103168","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Studies on the enhanced properties of nanocrystalline Zn–Ni 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additive"}]},{"@id":"https://cir.nii.ac.jp/crid/1360861291212517888","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effect of additives on the corrosion mechanism of nanocrystalline zinc–nickel alloys in an alkaline bath"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520765505920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Behavior of Zinc Electrode in Alkaline Electrolytes: I . A Kinetic Analysis of Cathodic Deposition"}]},{"@id":"https://cir.nii.ac.jp/crid/1361699995338942464","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Characterization of thin Zn–Ni alloy coatings electrodeposited on low carbon steel"}]},{"@id":"https://cir.nii.ac.jp/crid/1362262944307380480","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electrochemical studies of Zn–Ni alloy coatings from non-cyanide alkaline bath containing tartrate as complexing agent"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544418685866496","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Study of corrosion performance of electrodeposited nanocrystalline Zn–Ni alloy coatings"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419923091584","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Corrosion resistance of phosphated Zn–Ni alloy 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automobiles"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206481234176","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Electrodeposition Behavior of Zn-Ni Alloy from Alkaline Zincate Solution"},{"@language":"ja","@value":"アルカリジンケート浴からの Zn-Ni 合金電析挙動"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206489414400","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Electrodeposition Behavior of Zn–Ni Alloys from an Alkaline Zincate Solution Containing Ethylenediamine"},{"@language":"ja","@value":"エチレンジアミンを含むアルカリジンケート浴からのZn-Ni合金電析挙動"},{"@language":"ja-Kana","@value":"エチレンジアミン オ フクム アルカリジンケートヨク カラ ノ Zn-Ni ゴウキンデンセキキョドウ"},{"@value":"Electrodeposition Behavior of Zn-Ni alloy from Alkaline Zincate Solution Containing Ethylenediamine"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206489416704","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Electrodeposition Behavior of Zn–Co Alloys from an Alkaline Zincate Solution Containing Triethanolamine"},{"@language":"ja","@value":"トリエタノールアミンを含むアルカリジンケート浴からのZn-Co合金電析挙動"},{"@language":"ja-Kana","@value":"トリエタノールアミン オ フクム アルカリジンケートヨク カラ ノ Zn-Co ゴウキンデンセキキョドウ"},{"@value":"Electrodeposition Behavior of Zn-Co Alloy from Alkaline Zincate Solution Containing Triethanolamine"}]},{"@id":"https://cir.nii.ac.jp/crid/1390011340283965696","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Solution Temperature on Electrodeposition Behavior of Zn–Ni Alloy from Alkaline Zincate Solution"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679095592192","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Corrosion of Zn-Ni alloy films electroplated on iron."},{"@value":"鉄表面上のＺｎ‐Ｎｉ合金めっき皮膜の腐食"},{"@language":"ja-Kana","@value":"テツ ヒョウメンジョウ ノ Zn Ni ゴウキン メッキ ヒマク ノ フショク"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679226841088","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Electrodeposition Behavior of a Zn–Ni Alloy in an Alkaline Zincate Solution"},{"@value":"Electrodeposition Behavior of a Zn&ndash;Ni Alloy in an Alkaline Zincate Solution"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679226893568","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Mechanism of Anomalous Type Electrodeposition of Fe-Ni Alloys from Sulfate Solutions"},{"@language":"ja","@value":"硫酸塩浴からの変則型Fe-Ni合金電析の機構"},{"@language":"ja-Kana","@value":"リュウサンエンヨク カラ ノ ヘンソクガタ Fe Ni ゴウキンデンセキ ノ キコウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680159051392","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"Ni-Zn合金電気めつき鋼板の耐食性"},{"@language":"en","@value":"Corrosion-resistance of Electroplated Ni-Zn Alloy Steel Sheet"},{"@value":"Ni-Zn合金電気めっき鋼板の耐食性"},{"@language":"ja-Kana","@value":"Ni Zn ゴウキン デンキ メッキ コウハン ノ タイショクセイ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680159280384","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"非水溶媒浴を用いた亜鉛系合金の電析機構の検討"},{"@language":"en","@value":"Verification of Deposition Mechanism of Zinc Alloys Using Non-aqueous Plating Solutions"},{"@language":"ja-Kana","@value":"ヒスイヨウバイヨク オ モチイタ アエンケイ ゴウキン ノ デンセキ キコウ ノ ケントウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680159559552","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"溶融Zn-Al-Mg系合金めっき鋼板の促進腐食環境下における耐食性と防食機構"},{"@language":"en","@value":"Corrosion Resistance and Protection Mechanism of Hot-dip Zn-Al-Mg Alloy Coated Steel Sheetunder Accelerated Corrosion Environment"},{"@value":"表面処理・腐食 溶融Zn-Al-Mg系合金めっき鋼板の促進腐食環境下における耐食性と防食機構"},{"@language":"ja-Kana","@value":"ヒョウメン ショリ フショク ヨウユウ Zn Al Mgケイ ゴウキンメッキ コウハン ノ ソクシン フショク カンキョウ カ ニ オケル タイショクセイ ト ボウショク キコウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282681236152320","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"X-ray Analysis"},{"@language":"ja","@value":"X線分析"}]},{"@id":"https://cir.nii.ac.jp/crid/1390289068497729792","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Effect of Reaction Product of Epichlorohydrin and Imidazole on the Electrodeposition 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