Coating of 2D Flexible Metal–Organic Frameworks on Metal Nanocrystals

DOI Web Site 1 Citations 40 References Open Access
  • Ogiwara Naoki
    Division of Chemistry, Graduate School of Science, Kyoto University
  • Kobayashi Hirokazu
    Division of Chemistry, Graduate School of Science, Kyoto University PRESTO, Japan Science and Technology Agency
  • Kobayashi Keigo
    Division of Chemistry, Graduate School of Science, Kyoto University
  • Yamamoto Tomokazu
    The Ultramicroscopy Research Center, Kyushu University Department of Applied Quantum Physics and Nuclear Engineering, Graduate School of Engineering, Kyushu University
  • Toriyama Takaaki
    The Ultramicroscopy Research Center, Kyushu University
  • Matsumura Syo
    The Ultramicroscopy Research Center, Kyushu University Department of Applied Quantum Physics and Nuclear Engineering, Graduate School of Engineering, Kyushu University INAMORI, Frontier Research Center, Kyushu University
  • Kitagawa Hiroshi
    Division of Chemistry, Graduate School of Science, Kyoto University INAMORI, Frontier Research Center, Kyushu University Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University

Abstract

<p>We report, for the first time, metal (Pd) nanocrystals (NCs) covered with a 2D flexible metal–organic framework (MOF) of [Zn(NO2-ip)(bpy)]n (NO2-ip: 5-nitro-isophthalate, bpy: 4,4′-bipyridine). The hybrid materials were characterized by powder X-ray diffraction measurements and transmission electron microscope techniques. The CO2 sorption and hydrogen storage properties revealed that both the flexible porous character of the MOF and the hydrogen absorption ability of Pd NCs were compatible in the hybrid.</p>

Journal

  • Chemistry Letters

    Chemistry Letters 48 (2), 173-176, 2019-02-05

    The Chemical Society of Japan

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