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A Reliable Method to Create Adjacent Acid-Base Pair Sites on Silica through Hydrolysis of Pre-anchored Amide

DOI Web Site 30 References Open Access

Abstract

<p>A method to create adjacent acid-base pair sites, which are carboxyl and amino groups, respectively, on silica through hydrolysis of pre-anchored amide is proposed. This method can produce an adjacent acid-base pair site. The catalyst showed excellent catalytic performance for aldol condensation of 4-nitrobenzaldehyde with acetone, overwhelming the catalyst having only amino group and an acid-base catalyst prepared in a conventional manner.</p>

Journal

  • Chemistry Letters

    Chemistry Letters 49 (1), 71-74, 2020-01-05

    The Chemical Society of Japan

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