Photooxidation Products from a Marine Cadinane Sesquiterpenoid

DOI Web Site 参考文献11件
  • Kurnianda Viqqi
    Department of Chemistry, Biology and Marine Science, University of the Ryukyus
  • Fujimura Hiroyuki
    Department of Chemistry, Biology and Marine Science, University of the Ryukyus
  • Kanna Yoko
    Department of Chemistry, Biology and Marine Science, University of the Ryukyus
  • Tanaka Junichi
    Department of Chemistry, Biology and Marine Science, University of the Ryukyus

抄録

<p>To show that artifacts can readily form during research on marine natural products, a common marine sesquiterpenoid 1 was treated with sunlight in the presence of a pigment. Another set of solutions were prepared and kept in shade under the bench for two weeks as negative controls. As a result, four oxygenated derivatives 2–5 were obtained. A unique structure of a highly oxidized molecule 5 was solved by X-ray crystallography.</p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 50 (2), 220-222, 2021-02-05

    公益社団法人 日本化学会

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