{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390574666166232576.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.2320/matertrans.mt-m2021246"}},{"identifier":{"@type":"HDL","@value":"https://hdl.handle.net/2324/7173590"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"032367115"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/032367115"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I032367115"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/matertrans/63/9/63_MT-M2021246/_pdf"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Effects of Sulfur and Phosphorus on Binder Decomposition Behavior of Nickel Powder"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"<p>Fine Ni particles are utilized as internal electrode materials for multilayer ceramic capacitors. Despite extensive research, the effects of the surface properties (additional elements) remain unclear. To the best of our knowledge, the present study is the first to demonstrate the effects of the addition of sulfur (S) and phosphorus (P) on surface modification and binder decomposition during the production of fine Ni particles. Scanning electron microscopy, X-ray diffractometry, thermogravimetry-differential thermal analysis, hydrogen temperature-programmed reduction, temperature-programmed decomposition, and X-ray photoelectron spectroscopy were performed to analyze non-doped Ni, S-doped Ni and P-doped Ni powder. S existed as S–O or Ni–S on the particle surface in the S-doped Ni powder, whereas P existed solely as P–O on the particle surface in the P-doped Ni powder. When formed into a paste with these powders, the decomposition temperature of the binder is lower than that of the binder alone owing to the catalytic effect of the unmodified surface of Ni in non-doped Ni. However, the catalyst poisoning effect of S in S-doped Ni and the coating effect of P–O in P-doped Ni suppressed the lowering of the binder decomposition temperature due to the catalysis of the Ni surface. The results of the present study are expected to inspire future research on the optimization of the manufacturing process of multilayer ceramic capacitors.</p>"}],"abstractLicenseFlag":"disallow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410574666166232577","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Teruya Seiyu"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Materials, Kyushu University"},{"@language":"en","@value":"Shoei Chemical Inc."}]},{"@id":"https://cir.nii.ac.jp/crid/1410574666166232576","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Saito Noritaka"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Materials, Kyushu University"}]},{"@id":"https://cir.nii.ac.jp/crid/1410574666166232578","@type":"Researcher","foaf:name":[{"@language":"en","@value":"Nakashima Kunihiko"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Materials, Kyushu University"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"13459678"},{"@type":"LISSN","@value":"13459678"},{"@type":"EISSN","@value":"13475320"},{"@type":"NDL_BIB_ID","@value":"000000163280"},{"@type":"ISSN","@value":"13459678"},{"@type":"NCID","@value":"AA1151294X"}],"prism:publicationName":[{"@language":"en","@value":"MATERIALS TRANSACTIONS"},{"@language":"ja","@value":"MATERIALS TRANSACTIONS"},{"@language":"en","@value":"Mater. Trans."},{"@language":"ja","@value":"Mater. Trans."}],"dc:publisher":[{"@language":"en","@value":"The Japan Institute of Metals and Materials"},{"@language":"ja","@value":"公益社団法人 日本金属学会"}],"prism:publicationDate":"2022-09-01","prism:volume":"63","prism:number":"9","prism:startingPage":"1273","prism:endingPage":"1280"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/032367115"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I032367115"},{"@id":"https://www.jstage.jst.go.jp/article/matertrans/63/9/63_MT-M2021246/_pdf"}],"availableAt":"2022-09-01","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=sulfur","dc:title":"sulfur"},{"@id":"https://cir.nii.ac.jp/all?q=phosphorus","dc:title":"phosphorus"},{"@id":"https://cir.nii.ac.jp/all?q=catalyst","dc:title":"catalyst"},{"@id":"https://cir.nii.ac.jp/all?q=binder%20decomposition","dc:title":"binder decomposition"},{"@id":"https://cir.nii.ac.jp/all?q=Ni%20electrode%20paste","dc:title":"Ni electrode paste"},{"@id":"https://cir.nii.ac.jp/all?q=multilayer%20capacitor","dc:title":"multilayer capacitor"}],"dcterms:subject":[{"subjectScheme":"Other","notation":[{"@language":"en","@value":"sulfur"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"phosphorus"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"catalyst"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"binder decomposition"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Ni electrode paste"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"multilayer capacitor"}]}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360292620404943104","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Separation of particle size and lattice strain in integral breadth measurements"}]},{"@id":"https://cir.nii.ac.jp/crid/1360861294165977728","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Thermal degradation of biodegradable blends of polyethylene with cellulose and ethylcellulose"}]},{"@id":"https://cir.nii.ac.jp/crid/1361981470303768576","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Effect of boron, carbon, phosphorus and sulphur on intergranular cohesion in iron"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388843745659776","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Thermotropic liquid crystallinity, thermal decomposition behavior, and aggregated structure of poly(propylene carbonate)/ethyl cellulose blends"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204512581376","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Catalytic Activity of Metal Particles in the Binder Burn-out of Conductor Paste"},{"@value":"導電ペーストの脱バインダー過程における金属粒子の触媒作用"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205248345088","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Dependence of Electrode Ni Paste Properties on the Amount of Added BaTiO3 Powder."},{"@value":"ＭＬＣ内部電極用Ｎｉペースト特性に及ぼすＢａＴｉＯ３共材微粒子添加量の影響"},{"@language":"ja-Kana","@value":"MLC ナイブ デンキョクヨウ Ni ペースト トクセイ ニ オヨボス BaTi03 キョウザイ ビリュウシ テンカリョウ ノ エイキョウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205277489024","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"The Effect of Addition Amounts and Particle Sizes of BaTiO3 on Nickel Electrode Paste"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001205278079488","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Preparation and Evaluation of Next-Generation Ni Multilayer Ceramic Chip Capacitor Electrode Using Ni Flake Powder"},{"@language":"ja","@value":"Ni フレーク粉を用いた次世代 Ni-MLCC 電極の作製と評価"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001206351198976","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"セルロースの熱分解反応と分子機構"},{"@language":"en","@value":"Reactions and Molecular Mechanisms of Cellulose Pyrolysis"},{"@language":"ja-Kana","@value":"セルロース ノ ネツ ブンカイ ハンノウ ト ブンシ キコウ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282679490196736","@type":"Article","resourceType":"学術雑誌論文(journal article)","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Prepazation of Ni/BaTiO3 Core-shell Particle by Spray Drying Process"},{"@language":"ja","@value":"噴霧乾燥法によるＮｉ／ＢａＴｉＯ３コアシェル粒子の合成"},{"@language":"ja-Kana","@value":"フンム カンソウホウ ニ ヨル Ni BaTiO3 コアシェル リュウシ ノ ゴウセイ"}]},{"@id":"https://cir.nii.ac.jp/crid/1390282680108807424","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Studies on Catalytic Activities of Various Silica-Supported Nickel Catalysts for the Steam Reforming of Hydrocarbons by Means of Sulfur Poisoning"},{"@value":"炭化水素の水蒸気改質に用いる各種ニッケル触媒のイオウ被毒による活性比較"},{"@language":"ja-Kana","@value":"タンカスイソ ノ スイジョウキ カイシツ ニ モチイル カクシュ ニッケル ショクバイ ノ イオウ ヒドク ニ ヨル カッセイ ヒカク"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:2009843328"},{"@type":"IRDB","@value":"oai:irdb.nii.ac.jp:01211:0006217695"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I032367115"},{"@type":"CROSSREF","@value":"10.2320/matertrans.mt-m2021246"},{"@type":"OPENAIRE","@value":"doi_________::6ac236ce1a86eb09820776efaf4262b1"}]}