{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390845713075826432.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.5796/electrochemistry.72.266"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"6915350"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/6915350"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I6915350"}},{"identifier":{"@type":"URI","@value":"https://www.jstage.jst.go.jp/article/electrochemistry/72/4/72_266/_pdf"}},{"identifier":{"@type":"NAID","@value":"10012346264"}}],"dc:title":[{"@language":"en","@value":"New Electrochemical Process for CO<sub>2</sub> Reduction to from Formic Acid from Combustion Flue Gases"},{"@value":"New Electrochemical Precess for CO2 Reduction to from Formic Acid from Combustion Flue Gases"}],"dc:language":"en","description":[{"type":"abstract","notation":[{"@language":"en","@value":"<p>Flow cell technologies for electrochemical reactors were applied to the system for carbon dioxide absorption and its electrochemical reduction. Small flow-by type reactors with two chambers separated by a sheet of ion-exchange membrane were employed for both CO<sub>2</sub> absorbtion and reduction. Absorbtion of CO<sub>2</sub> into phosphate buffer solutions through the ion exchange membrane and succeeding electrochemical reduction of the absorbed CO<sub>2</sub> were studied; and the opimum conditions to form formic acid with high current efficiency were discussed. Formic acid is expected to be available to chemiluminescent reagents for oxidant detections and chemical lamps. Almost 100% in current efficiency of CO<sub>2</sub> reduction to form formic acid was realized by using In impregnated lead wire cathode. The applied cell voltage was reduced to under 1.5 V due to sulfur dioxide absorption into counter electrode solution.</p>"}],"abstractLicenseFlag":"allow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410845713075407360","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001161231"}],"foaf:name":[{"@language":"en","@value":"AKAHORI Yumi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Depertment of Industrial Chemistry, Meiji University, School of Science and Technology"}]},{"@id":"https://cir.nii.ac.jp/crid/1410845713075826432","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001161560"}],"foaf:name":[{"@language":"en","@value":"IWANAGA Nahoko"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Depertment of Industrial Chemistry, Meiji University, School of Science and Technology"}]},{"@id":"https://cir.nii.ac.jp/crid/1410845713075826435","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001161233"}],"foaf:name":[{"@language":"en","@value":"KATO Yumi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Japan Analysis & Evaluation Center"}]},{"@id":"https://cir.nii.ac.jp/crid/1410845713075826433","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001161230"}],"foaf:name":[{"@language":"en","@value":"HAMAMOTO Osamu"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Steel structure & Logistic Systems Hq., Mitsui Engineering & Shipbuilding Co., Ltd."}]},{"@id":"https://cir.nii.ac.jp/crid/1410845713075826436","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000001161234"}],"foaf:name":[{"@language":"en","@value":"ISHII Mikita"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Depertment of Industrial Chemistry, Meiji University, School of Science and Technology"},{"@language":"en","@value":"Japan Analysis & Evaluation Center"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"13443542"},{"@type":"LISSN","@value":"13443542"},{"@type":"EISSN","@value":"21862451"},{"@type":"NDL_BIB_ID","@value":"000000031819"},{"@type":"ISSN","@value":"13443542"},{"@type":"NCID","@value":"AN00151637"}],"prism:publicationName":[{"@language":"en","@value":"Electrochemistry"},{"@language":"en","@value":"Electrochemistry"}],"dc:publisher":[{"@language":"en","@value":"The Electrochemical Society of Japan"},{"@language":"ja","@value":"公益社団法人　電気化学会"}],"prism:publicationDate":"2004-04-05","prism:volume":"72","prism:number":"4","prism:startingPage":"266","prism:endingPage":"270"},"reviewed":"false","dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"http://id.ndl.go.jp/bib/6915350"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I6915350"},{"@id":"https://www.jstage.jst.go.jp/article/electrochemistry/72/4/72_266/_pdf"}],"availableAt":"2004-04-05","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Carbon%20Dioxide","dc:title":"Carbon Dioxide"},{"@id":"https://cir.nii.ac.jp/all?q=Electrochemical%20Reactor","dc:title":"Electrochemical Reactor"},{"@id":"https://cir.nii.ac.jp/all?q=Formic%20Acid","dc:title":"Formic Acid"},{"@id":"https://cir.nii.ac.jp/all?q=Lead%20Wire%20Electrodes","dc:title":"Lead Wire Electrodes"}],"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1360292618865210240","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Electroreduction of carbon dioxide on gas-diffusion electrodes modified by metal phthalocyanines"}]},{"@id":"https://cir.nii.ac.jp/crid/1360574095848258560","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Current Distributions on Plane, Parallel Electrodes in Channel Flow"}]},{"@id":"https://cir.nii.ac.jp/crid/1361418520020882048","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"Use of gas-diffusion electrodes for high-rate electrochemical reduction of carbon dioxide. 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Reduction at lead, indium- and tin-impregnated electrodes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544419974976256","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The Electroreduction of Carbon Dioxide and Formic Acid on Tin and Indium Electrodes"}]},{"@id":"https://cir.nii.ac.jp/crid/1362544420952719360","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The behaviour of porous electrodes in a flow-by regime—I. theoretical study"}]},{"@id":"https://cir.nii.ac.jp/crid/1363388845817310720","@type":"Article","relationType":["references","cites"],"jpcoar:relatedTitle":[{"@value":"A comparison between flow-through and flow-by porous electrodes for redox energy storage"}]},{"@id":"https://cir.nii.ac.jp/crid/1363670319893804544","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@value":"The behaviour of porous electrodes in a flow-by regime—II. experimental study"}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204118253952","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"Electrochemical reduction of carbon dioxide at various metal electrodes in aqueous potassium hydrogen carbonate solution."}]},{"@id":"https://cir.nii.ac.jp/crid/1390001204578291328","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"en","@value":"PRODUCTION OF CO AND CH<SUB>4</SUB> IN ELECTROCHEMICAL REDUCTION OF CO<SUB>2</SUB> AT METAL ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION"},{"@value":"PRODUCTION OF CO AND CH4 IN ELECTROCHEMICAL REDUCTION OF CO2 AT METAL ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION"},{"@value":"Production of CO and CH4 in electrochemical reduction of CO2 at metal electrodes in aqueous hydrocarbonate solution"}]},{"@id":"https://cir.nii.ac.jp/crid/1390564227306462848","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"炭酸ガスと電気化学 1.炭酸ガスの電気化学還元"},{"@value":"炭酸ガスの電気化学還元"},{"@language":"ja-Kana","@value":"タンサン ガス ノ デンキ カガク カンゲン"}]},{"@id":"https://cir.nii.ac.jp/crid/1390845702293649920","@type":"Article","relationType":["references"],"jpcoar:relatedTitle":[{"@language":"ja","@value":"レドックス・フロー型電池の研究開発のための小型フロー・セル"},{"@language":"ja-Kana","@value":"レドックス フローガタ デンチ ノ ケンキュウ カイハツ ノ タメ ノ コガタ"}]},{"@id":"https://cir.nii.ac.jp/crid/1570009750182973568","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1570291225159682304","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1570572699139789568","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571698599046629888","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1571980075019947008","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572261549996656768","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572261549996660224","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572543024973367680","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572543024973373568","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1572824499950080640","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974044385408","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974926698880","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974926788480","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573105974926794880","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573387449903503232","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1573668924880211584","@type":"Article","relationType":["cites"]},{"@id":"https://cir.nii.ac.jp/crid/1574231874833539840","@type":"Article","relationType":["cites"]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:2007246704"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I6915350"},{"@type":"CROSSREF","@value":"10.5796/electrochemistry.72.266"},{"@type":"CIA","@value":"10012346264"},{"@type":"OPENAIRE","@value":"doi_dedup___::64a1c4820892a634f78178b7f7fd2dfd"}]}