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Reactions of 1-Alkynes with a Molybdenum-Silyl Complex: Stable σ-Acetylide Complexes Containing a Pentadentate Ligand Comprised of a P<sub>2</sub>SiP<sub>2</sub> Framework

  • Minato Makoto
    Department of Materials Chemistry, Faculty of Engineering, Yokohama National University
  • Watanabe Kyosuke
    Department of Materials Chemistry, Faculty of Engineering, Yokohama National University
  • Maeda Kengo
    Department of Materials Chemistry, Faculty of Engineering, Yokohama National University

Bibliographic Information

Other Title
  • Reactions of 1-Alkynes with a Molybdenum-Silyl Complex: Stable σ-Acetylide Complexes Containing a Pentadentate Ligand Comprised of a P2SiP2 Framework

Abstract

<p>Reactions of molybdenum-silyl hydrido complex 2 ([MoH3{Si(Ph)[Ph2PCH2CH2P(Ph)C6H4-o]2}]) with 1.5 equiv of 1-alkynes RC≡CH occur readily at room temperature giving σ-acetylide complexes ([MoH2{Si(Ph)[Ph2PCH2CH2P(Ph)C6H4-o]2}(C≡CR)]: R = Ph (3a), t-Bu (3b)), in which the acetylide ligands ligate at the site opposite to the Si atom.</p>

Journal

  • Chemistry Letters

    Chemistry Letters 48 (12), 1526-1528, 2019-12-05

    The Chemical Society of Japan

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