{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1390860841872054016.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.57415/xshinpo.44.0_261"}},{"identifier":{"@type":"URI","@value":"https://tokushima-u.repo.nii.ac.jp/records/2004412"}},{"identifier":{"@type":"NDL_BIB_ID","@value":"024584788"}},{"identifier":{"@type":"URI","@value":"http://id.ndl.go.jp/bib/024584788"}},{"identifier":{"@type":"URI","@value":"https://ndlsearch.ndl.go.jp/books/R000000004-I024584788"}},{"identifier":{"@type":"NAID","@value":"120006411718"}}],"resourceType":"学術雑誌論文(journal article)","dc:title":[{"@language":"en","@value":"Pilot Study of Devises for Chemical Reactions with High Electric Field of Pyroelectric Crystal"},{"@language":"ja","@value":"焦電結晶を用いた密封系小型高電場発生ユニットの製作と電場触媒反応への応用に向けた試み"},{"@language":"ja-Kana","@value":"ショウデンケッショウ オ モチイタ ミップウケイ コガタ コウデンバ ハッセイ ユニット ノ セイサク ト デンバ ショクバイ ハンノウ エ ノ オウヨウ ニ ムケタ ココロミ"}],"dc:language":"ja","description":[{"type":"abstract","notation":[{"@language":"en","@value":"<p>Compact devices for high electric field generator using a different aspect ratio of pyroelectric LiTaO<sub>3</sub> single crystal and a Peltier device were assembled. Measurement of X-ray emitted upon the thermal changing was carried out to evaluate the induced electric field onto surface of the z-plane of LiTaO<sub>3</sub>. The formed electric field per length of the z-axis for thin-type (10 × 10 × 2 mm) was twice larger than that of pillar-type (3 × 3 × 10 mm). The attachment of Pt foil onto the surface of z-plane little affected on X-ray emission behavior. The flange-type generator with thin-type LiTaO<sub>3</sub> single crystal was also assembled to construct a reactor for chemical reactions with induced high electric field of a pyroelectric crystal. The outgassing behavior from a reaction vessel was examined.</p>"},{"@language":"ja","@value":"<p>タンタル酸リチウム単結晶の温度変化に伴って形成する高電場を電場触媒反応に応用することを目標とし，反応基質を導入可能な密封系小型高電場発生ユニットを製作した．z軸長に対するz面の面積が異なる二種類の単結晶を用いてX線発生実験を行ったところ，単位z軸長あたりの生成した電場は薄片型結晶の方が大きかった．単結晶表面に白金箔を添加した状態でも，白金箔の特性X線が最高エネルギー22 keVの白色X線に重なって観測された．製作した密封空間のガス放出挙動を質量分析計で測定した．</p>"}],"abstractLicenseFlag":"allow"}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1410016272552333568","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000384269242"}],"foaf:name":[{"@language":"en","@value":"YAMAOKA Rie"},{"@language":"ja","@value":"山岡 理恵"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Regional Sciences, Graduate School of Integrated Arts and Sciences, The University of Tokushima"},{"@language":"ja","@value":"徳島大学大学院総合科学教育部地域科学専攻"}]},{"@id":"https://cir.nii.ac.jp/crid/1410860841872054016","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000384269260"}],"foaf:name":[{"@language":"en","@value":"SAKAGAMI Chisato"},{"@language":"ja","@value":"坂上 知里"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"徳島大学総合科学部総合理数学科"},{"@language":"en","@value":"Department of Mathematical and Material Sciences, Faculty of Integrated Arts and Sciences, The University of Tokushima"}]},{"@id":"https://cir.nii.ac.jp/crid/1410016272552333569","@type":"Researcher","personIdentifier":[{"@type":"NRID","@value":"9000384269261"}],"foaf:name":[{"@language":"en","@value":"UMAKI Ryosuke"},{"@language":"ja","@value":"馬木 良輔"}],"jpcoar:affiliationName":[{"@language":"ja","@value":"徳島大学総合科学部総合理数学科"},{"@language":"en","@value":"Department of Mathematical and Material Sciences, Faculty of Integrated Arts and Sciences, The University of Tokushima"}]},{"@id":"https://cir.nii.ac.jp/crid/1420845751165004800","@type":"Researcher","personIdentifier":[{"@type":"KAKEN_RESEARCHERS","@value":"70361756"},{"@type":"NRID","@value":"1000070361756"},{"@type":"ORCID","@value":"0000-0001-9586-6584"},{"@type":"NRID","@value":"9000016408192"},{"@type":"NRID","@value":"9000259311136"},{"@type":"NRID","@value":"9000401890842"},{"@type":"NRID","@value":"9000384269319"},{"@type":"NRID","@value":"9000384269283"},{"@type":"NRID","@value":"9000402283832"},{"@type":"NRID","@value":"9000402070098"},{"@type":"NRID","@value":"9000257792131"},{"@type":"NRID","@value":"9000258197295"},{"@type":"NRID","@value":"9000003248725"},{"@type":"NRID","@value":"9000257794450"},{"@type":"NRID","@value":"9000411103199"},{"@type":"NRID","@value":"9000389942793"},{"@type":"NRID","@value":"9000401891232"},{"@type":"NRID","@value":"9000384269327"},{"@type":"NRID","@value":"9000406018483"},{"@type":"NRID","@value":"9000258197169"},{"@type":"NRID","@value":"9000001624210"},{"@type":"NRID","@value":"9000384269294"},{"@type":"NRID","@value":"9000402069689"},{"@type":"RESEARCHMAP","@value":"https://researchmap.jp/TYamamoto1213"}],"foaf:name":[{"@language":"ja","@value":"山本 孝"},{"@language":"en","@value":"YAMAMOTO Takashi"}],"jpcoar:affiliationName":[{"@language":"en","@value":"Department of Regional Sciences, Graduate School of Integrated Arts and Sciences, The University of Tokushima"},{"@language":"ja","@value":"徳島大学大学院総合科学教育部地域科学専攻"},{"@language":"ja","@value":"徳島大学総合科学部総合理数学科"},{"@language":"en","@value":"Department of Mathematical and Material Sciences, Faculty of Integrated Arts and Sciences, The University of Tokushima"},{"@language":"ja","@value":"徳島大学大学院ソシオ・アーツ・アンド・サイエンス研究部"},{"@language":"en","@value":"Institute of Scio-Arts and Sciences, The University of Tokushima"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"09117806"},{"@type":"EISSN","@value":"27583651"},{"@type":"ISSN","@value":"09117806"},{"@type":"NDL_BIB_ID","@value":"000000048610"},{"@type":"LISSN","@value":"09117806"},{"@type":"NCID","@value":"AN0000592X"}],"prism:publicationName":[{"@language":"en","@value":"Advances in X-Ray Chemical Analysis, Japan"},{"@language":"ja","@value":"Ｘ線分析の進歩"},{"@language":"en","@value":"Adv. X-Ray Chem. Anal. Jpn."}],"dc:publisher":[{"@language":"en","@value":"The Discussion Group of X-Ray Analysis, The Japan Society for Analytical Chemistry"},{"@language":"ja","@value":"公益社団法人 日本分析化学会　X線分析研究懇談会"}],"prism:publicationDate":"2013-03-31","prism:volume":"44","prism:number":"0","prism:startingPage":"261","prism:endingPage":"267"},"dcterms:accessRights":"http://purl.org/coar/access_right/c_abf2","url":[{"@id":"https://tokushima-u.repo.nii.ac.jp/records/2004412"},{"@id":"http://id.ndl.go.jp/bib/024584788"},{"@id":"https://ndlsearch.ndl.go.jp/books/R000000004-I024584788"},{"@id":"http://repo.lib.tokushima-u.ac.jp/111224"}],"availableAt":"2013-03-31","foaf:topic":[{"@id":"https://cir.nii.ac.jp/all?q=Pyroelectric%20crystal","dc:title":"Pyroelectric crystal"},{"@id":"https://cir.nii.ac.jp/all?q=LiTaO%3Csub%3E3%3C/sub%3E","dc:title":"LiTaO<sub>3</sub>"},{"@id":"https://cir.nii.ac.jp/all?q=X-ray%20emission","dc:title":"X-ray emission"},{"@id":"https://cir.nii.ac.jp/all?q=Electric%20field%20assisted%20reaction","dc:title":"Electric field assisted reaction"},{"@id":"https://cir.nii.ac.jp/all?q=%E7%84%A6%E9%9B%BB%E7%B5%90%E6%99%B6","dc:title":"焦電結晶"},{"@id":"https://cir.nii.ac.jp/all?q=%E3%82%BF%E3%83%B3%E3%82%BF%E3%83%AB%E9%85%B8%E3%83%AA%E3%83%81%E3%82%A6%E3%83%A0","dc:title":"タンタル酸リチウム"},{"@id":"https://cir.nii.ac.jp/all?q=X%E7%B7%9A%E7%99%BA%E7%94%9F","dc:title":"X線発生"},{"@id":"https://cir.nii.ac.jp/all?q=%E9%9B%BB%E5%A0%B4%E8%A7%A6%E5%AA%92%E5%8F%8D%E5%BF%9C","dc:title":"電場触媒反応"}],"dcterms:subject":[{"subjectScheme":"Other","notation":[{"@language":"ja","@value":"焦電結晶"}]},{"subjectScheme":"Other","notation":[{"@language":"ja","@value":"タンタル酸リチウム"}]},{"subjectScheme":"Other","notation":[{"@language":"ja","@value":"X線発生"}]},{"subjectScheme":"Other","notation":[{"@language":"ja","@value":"電場触媒反応"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Pyroelectric crystal"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"LiTaO3"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"X-ray emission"}]},{"subjectScheme":"Other","notation":[{"@language":"en","@value":"Electric field assisted reaction"}]}],"dataSourceIdentifier":[{"@type":"JALC","@value":"oai:japanlinkcenter.org:2011684271"},{"@type":"IRDB","@value":"oai:irdb.nii.ac.jp:00906:0006776365"},{"@type":"NDL_SEARCH","@value":"oai:ndlsearch.ndl.go.jp:R000000004-I024584788"},{"@type":"CIA","@value":"120006411718"}]}