1,3-Dipolar Cycloaddition Leading to N-Acylated Pyrrolidines and 2,5-Dihydropyrroles

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Published
1983-11-25
Publisher
The Pharmaceutical Society of Japan

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Description

Dipolar cycloaddition of an intermediary N-acyltrimethylsilylmethyliminium salt formed from N-(benzylidene) trimethylsilylmethylamine and acyl chloride to conjugated alkenes or alkines gave N-acylpyrrolidines or N-acyl-2,5-dihydropyrroles, respectively. The stereochemistry of all the products was established.

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