{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1872272492454140928.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1021/ic050453a"}},{"identifier":{"@type":"PMID","@value":"16124799"}}],"dc:title":[{"@value":"Syntheses, Structures, and Luminescent and Magnetic Properties of Novel Three-Dimensional Lanthanide Complexes with 1,3,5-Benzenetriacetate"}],"description":[{"notation":[{"@value":"Five novel lanthanide complexes with the formulas [Nd(bta)(H2O)2.4.35H2O]n(1), [Sm(bta)(H2O)2.4.5H2O]n (2), [Eu(bta)(H2O).1.48H2O]n (3), [Tb(bta)(H2O).1.31H2O]n (4), and [Yb(bta)(H2O).H2O]n (5) (H3bta = 1,3,5-benzenetriacetic acid) have been prepared by using the corresponding lanthanide salt and H3bta. The results of an X-ray crystallographic analysis revealed that all the complexes have three-dimensional channel-like structures, in which the bta3- ligands adopt different coordination modes: monodentate and mu2-eta2:eta1-bridging coordination modes in 1, 2, and 5 and mu2-eta1:eta1-bridging and mu2-eta2:eta1-bridging coordination modes in 3 and 4, respectively. Complexes 1 and 2, as well as 3 and 4, are isostructural, respectively, in which all the Ln(III) (Ln = Nd, Sm, Eu, and Tb) atoms are nine-coordinated, while the Yb(III) atoms in complex 5 are eight-coordinated. Both complexes 3 and 4 showed strong luminescence upon excitation, and their luminescence decay curves fit well with single exponential decays of which the lifetime is 0.45 ms for 3 and 1.0 ms for 4. The magnetic properties of the complexes were investigated in the temperature range of 1.8-300 K."}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1892272492454140932","@type":"Researcher","foaf:name":[{"@value":"Wei-Yin Sun"}]},{"@id":"https://cir.nii.ac.jp/crid/1892272492454140934","@type":"Researcher","foaf:name":[{"@value":"Zheng-Hua Zhang"}]},{"@id":"https://cir.nii.ac.jp/crid/1892272492454140929","@type":"Researcher","foaf:name":[{"@value":"Ling-Yan Kong"}]},{"@id":"https://cir.nii.ac.jp/crid/1892272492454140928","@type":"Researcher","foaf:name":[{"@value":"Hiroyuki Kawaguchi"}]},{"@id":"https://cir.nii.ac.jp/crid/1892272492454140933","@type":"Researcher","foaf:name":[{"@value":"Norikazu Ueyama"}]},{"@id":"https://cir.nii.ac.jp/crid/1892272492454140931","@type":"Researcher","foaf:name":[{"@value":"Taka-aki Okamura"}]},{"@id":"https://cir.nii.ac.jp/crid/1892272492454140930","@type":"Researcher","foaf:name":[{"@value":"Yasuchika Hasegawa"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00201669"},{"@type":"EISSN","@value":"1520510X"}],"prism:publicationName":[{"@value":"Inorganic Chemistry"}],"dc:publisher":[{"@value":"American Chemical Society (ACS)"}],"prism:publicationDate":"2005-08-11","prism:volume":"44","prism:startingPage":"6219","prism:endingPage":"6227"},"relatedProduct":[{"@id":"https://cir.nii.ac.jp/crid/1880020692863328384","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 601805: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1880302168089178752","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 234680: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1881428067699167488","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 601804: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1882553968162901248","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 234681: Experimental Crystal Structure Determination"}]},{"@id":"https://cir.nii.ac.jp/crid/1883398392776885376","@type":"Dataset","relationType":["isSupplementedBy"],"jpcoar:relatedTitle":[{"@value":"CCDC 234682: Experimental Crystal Structure Determination"}]}],"dataSourceIdentifier":[{"@type":"OPENAIRE","@value":"doi_dedup___::54d853ffe0fa1470470f57665f54c2f4"}]}