{"@context":{"@vocab":"https://cir.nii.ac.jp/schema/1.0/","rdfs":"http://www.w3.org/2000/01/rdf-schema#","dc":"http://purl.org/dc/elements/1.1/","dcterms":"http://purl.org/dc/terms/","foaf":"http://xmlns.com/foaf/0.1/","prism":"http://prismstandard.org/namespaces/basic/2.0/","cinii":"http://ci.nii.ac.jp/ns/1.0/","datacite":"https://schema.datacite.org/meta/kernel-4/","ndl":"http://ndl.go.jp/dcndl/terms/","jpcoar":"https://github.com/JPCOAR/schema/blob/master/2.0/"},"@id":"https://cir.nii.ac.jp/crid/1873679867998934656.json","@type":"Article","productIdentifier":[{"identifier":{"@type":"DOI","@value":"10.1002/app.11625"}}],"dc:title":[{"@value":"Pervaporation properties of aromatic/nonaromatic hydrocarbons of crosslinked membranes of copolymers based on diethyl vinylbenzylphosphonate"}],"description":[{"notation":[{"@value":"<jats:title>Abstract</jats:title><jats:p>Copoly(diethyl vinylbenzylphosphonate/hydroxyethyl methacrylate) [copoly(VBP–HEMA)] and copoly(diethyl vinylbenzylphosphonate/vinylbenzyl chloride) [copoly(VBP–VBC)] were prepared and their membranes crosslinked by a reaction of ethylene glycol diglycidyl ether and ethylene diamine with, respectively, hydroxyl and methylene chloride groups in their side chains. Pervaporation (PV) and sorption of benzene–<jats:italic>n</jats:italic>‐hexane (Bz–Hx), benzene–cyclohexane (Bz–Cx), and toluene–<jats:italic>n</jats:italic>‐octane (Tol–<jats:italic>n</jats:italic>‐Ot) mixtures were investigated. The membranes were in a rubbery state and preferentially permeable to aromatics. They had higher specific permeation flux and a lower PV separation factor compared with the crosslinked membranes of methacrylate copolymers with analogous pendant groups. They displayed better PV performance for Tol–<jats:italic>n</jats:italic>‐Ot. Sorption isotherms of Bz–Hx mixtures were represented by the Flory–Rehner model. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 87: 2177–2185, 2003</jats:p>"}]}],"creator":[{"@id":"https://cir.nii.ac.jp/crid/1893679867998934656","@type":"Researcher","foaf:name":[{"@value":"Satoshi Hirakawa"}]},{"@id":"https://cir.nii.ac.jp/crid/1893679867998934787","@type":"Researcher","foaf:name":[{"@value":"Yong Wang"}]},{"@id":"https://cir.nii.ac.jp/crid/1893679867998934784","@type":"Researcher","foaf:name":[{"@value":"Kazuhiro Tanaka"}]},{"@id":"https://cir.nii.ac.jp/crid/1893679867998934785","@type":"Researcher","foaf:name":[{"@value":"Hidetoshi Kita"}]},{"@id":"https://cir.nii.ac.jp/crid/1893679867998934786","@type":"Researcher","foaf:name":[{"@value":"Ken-ichi Okamoto"}]}],"publication":{"publicationIdentifier":[{"@type":"PISSN","@value":"00218995"},{"@type":"EISSN","@value":"10974628"}],"prism:publicationName":[{"@value":"Journal of Applied Polymer Science"}],"dc:publisher":[{"@value":"Wiley"}],"prism:publicationDate":"2003-01-13","prism:volume":"87","prism:startingPage":"2177","prism:endingPage":"2185"},"dataSourceIdentifier":[{"@type":"OPENAIRE","@value":"doi_dedup___::59d131707ef0c4937fc251090d3e5a12"}]}