Enhancing proton mobility and thermal stability in phosphate glasses with WO<sub>3</sub>: the mixed glass former effect in proton conducting glasses

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  • Aman Sharma
    Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan
  • Issei Suzuki
    Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan
  • Tomohiro Ishiyama
    Research Institute for Energy Conservation, Department of Energy and Environment, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan
  • Takahisa Omata
    Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

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説明

<jats:p>The replacement of PO<jats:sub>5/2</jats:sub> with WO<jats:sub>3</jats:sub> increased both proton mobility and thermal stability of proton conducting phosphate glass. The P–O–W linkages enhance the inter-phosphate chain proton migration and suppress viscous flow at elevated temperature.</jats:p>

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