Application of mononuclear metal complexes with a hexamethylene-dithiocarbamate ligand as photosensitizers for dye-sensitized solar cells

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[Abstract] We present a new approach using mononuclear metal complexes with a hexamethylene-dithiocarbamate ligand, [M(Hm—dtc)_n] (M = Cu^<2+>, n = 2 (1); M = Ni^<2+>, n = 2 (2); M = Co^<3+>, n = 3 (3); M = Fe^<3+>, n = 3 (4); Hm—dtc^- =hexamethylene-dithiocarbamate), as dye materials for dye—sensitized solar cells (DSSCs). DSSCs based on a [Cu(Hm—dtc)_2] dye exhibited relatively high power conversion efficiency due to their high short—circuit photocurrent density and long electron lifetime.

KURODA SOWA, Takayoshi

Departmental Bulletin Paper

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