Multiply-fused porphyrins-effects of extended π-conjugation on the optical and electrochemical properties

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  • Multiply-fused porphyrins—effects of extended π-conjugation on the optical and electrochemical properties

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A novel quadruply-fused porphyrin has been synthesized with a facilely prepared precursor in a high yield. A detailed comparison of the physical properties of a series of fused porphyrins revealed remarkable effects of the ring fusion on lowering LUMO levels rather than HOMO levels.

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