N-ビオチニル-アミノ-β-シクロデキストリンの合成
書誌事項
- タイトル別名
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- Synthesis of N-Biotinyl-amino-β-cyclodextrin
- N-ビオチニル-アミノ-β-シクロデキストリン ノ ゴウセイ
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説明
The fact that α-biotin serves as a covalently bound "C0_2 carrier" is now unequivocally established. Though model studies such as carboxylation on ureid l'-N-of biotin has been reported, no appropriate biomimetic model study for a "C0_2 carrier" has been carried out. The titled compound(I)in which the biotinyl group is bound to an amide linkage withβ-cyclodextrin, was prepared with active-ester method in good yield. Compound I was purified by taking with preparative HPLC. The structure of (I) was providedby ^1H-nmr, ^<13>C-nmr, elemental analysis, HPLC and the paper choromatography of hydrolyzates, and decided to be 6-(mono-N-biotinyl)-amino-β-cyclodextrin.
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KJ00002409580
論文
Article
収録刊行物
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- 東京工芸大学工学部紀要
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東京工芸大学工学部紀要 7 (1), 47-52, 1984
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詳細情報 詳細情報について
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- CRID
- 1050001202674643072
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- NII論文ID
- 110001132460
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- NII書誌ID
- AN00159741
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- ISSN
- 03876055
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- 本文言語コード
- ja
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- 資料種別
- departmental bulletin paper
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- データソース種別
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- IRDB
- CiNii Articles