<報文>ビスマスの帯融精製について

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  • ビスマス ノ タイユウセイセイ ニ ツイテ
  • <Original Papers>Zone-Refining of Bismuth

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Purification of electrolytic bismuth was attempted by means of the zone-refining. Impurities such as Pb and Cu were removed at the tail under various conditions, particularly, at the rate of 35 and 70mm/hr of zone speed. It was observed that the segregation of As was not significant. The distribution of impurities in Bi was quantitatively determined by the colorimetric and polarographic method. The effective segregation coefficient K is given as follows : K_<Pb>=0.06_7 for lead, K_<Cu>=0.08_7 for cupper and K_<As>=1 for arsenic.

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