<報文>輝水鉛鉱の浮選に関する研究(第3報) : 輝水鉛鉱によるジチオ炭酸塩およびジチオリン酸塩の吸着

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  • キスイエンコウ ノ フセン ニ カンスル ケンキュウ 3
  • <Original Papers>Studies on the Flotation of Molybdenite. (III) : Adsorption of Dithiocarbonate and Dithiophosphate by Molybdenite

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The adsorption of dithiocarbonate or dithiophosphate by molybdenite was studied by means of ultra-violet, visible, and infra-red spectrophotometries. Xanthate is strongly adsorbed on molybdenite, but dithiophosphate is adsorbed with weak molecular to strong chemical forces. With xanthate, adsorbed species on molybdenite can be recognized as dixanthogen, and with dithiophosphate as βis-(O, O-di-alkyldithiophosphoryl) disulfide. The reason for the formation of above-mentioned adsorbed species was discussed from the standpoint of semi-conductive properties of molybdenite in question.

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