FT-IR Spectroscopy of CO Produced by the Photodissociation of Hexafluoroacetylacetone

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Abstract

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Photochemistry of Hexafluoroacetylacetone has been studied by photoproduct analysis using infrared spectroscopy. Hexafluoroacetylacetone was irradiated by KrF excimer laser with the oscillation wavelength of 248 nm during 100 seconds and the photoproducts were analyzed by transmittance measurement of FT-IR in the spectral region between 3500 cm^<-1> and 1300 cm^<-1>. One of the photoproducts was CO. It was estimated that the formation efficiency of CO was approximately 0.6.

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