- 【Updated on May 12, 2025】 Integration of CiNii Dissertations and CiNii Books into CiNii Research
- Trial version of CiNii Research Knowledge Graph Search feature is available on CiNii Labs
- 【Updated on June 30, 2025】Suspension and deletion of data provided by Nikkei BP
- Regarding the recording of “Research Data” and “Evidence Data”
A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal-Organic Polyhedra
Search this article
Description
Porous molecular cages have a characteristic processability arising from their solubility, which allows their incorporation into porous materials. Attaining solubility often requires covalently bound functional groups that are unnecessary for porosity and which ultimately occupy free volume in the materials, decreasing their surface areas. Here, a method is described that takes advantage of the coordination bonds in metal–organic polyhedra (MOPs) to render insoluble MOPs soluble by reversibly attaching an alkyl‐functionalized ligand. We then use the newly soluble MOPs as monomers for supramolecular polymerization reactions, obtaining permanently porous, amorphous polymers with the shape of colloids and gels, which display increased gas uptake in comparison with materials made with covalently functionalized MOPs.
Journal
-
- Angewandte Chemie International Edition
-
Angewandte Chemie International Edition 58 (19), 6347-6350, 2019-05-06
Wiley
- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1050001338453522560
-
- NII Article ID
- 120006713551
-
- ISSN
- 14337851
- 15213773
- 15213757
- 00448249
-
- HANDLE
- 10261/200127
- 2433/243550
-
- PubMed
- 30848051
-
- Web Site
- https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201901668
- https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201901668
- https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.201901668
- https://onlinelibrary.wiley.com/doi/am-pdf/10.1002%2Fanie.201901668
- https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201901668
- https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201901668
- https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ange.201901668
-
- Text Lang
- en
-
- Article Type
- journal article
-
- Data Source
-
- IRDB
- Crossref
- CiNii Articles
- KAKEN
- OpenAIRE