Pd/TiO<sub>2</sub>-Photocatalyzed Self-Condensation of Primary Amines To Afford Secondary Amines at Ambient Temperature
書誌事項
- タイトル別名
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- Pd/TiO2-Photocatalyzed Self-Condensation of Primary Amines To Afford Secondary Amines at Ambient Temperature
説明
Symmetric secondary amines were synthesized by the self-condensation of primary amines over a palladium-loaded titanium dioxide (Pd/TiO2) photocatalyst. The reactions afforded a series of secondary amines in moderate to excellent isolated yields at ambient temperature (30 °C, in cyclopentyl methyl ether). Applicability for one-pot pharmaceutical synthesis was demonstrated by a photocatalytic reaction sequence of self-condensation of an amine followed by N-alkylation of the resulting secondary amine with an alcohol.
収録刊行物
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- Organic Letters
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Organic Letters 21 (2), 341-344, 2019-01-18
ACS Publications
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詳細情報 詳細情報について
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- CRID
- 1050001338813950080
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- NII論文ID
- 120006623817
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- ISSN
- 15237052
- 15237060
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- HANDLE
- 2237/00030148
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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