Large frequency dependence of lowered maximum dielectric constant temperature of LiTaO3 nanocrystals dispersed in mesoporous silicate

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A large frequency dependence of the maximum dielectric constant temperature was observed for LiTaO3 nanocrystals (the diameter 20 Å) dispersed in mesoporous silicate. At the applied field frequency of 100 kHz, the maximum temperatures in the real and imaginary parts were 365 and 345 °C, respectively. The maximum temperature in the real part is apparently lower than the paraelectric–ferroelectric transition temperature (645 °C) of bulk LiTaO3. The maximum temperature in the imaginary part rose from 285 to 420 °C with increasing frequency from 10 to 1000 kHz. Since the bulk LiTaO3 shows no relaxor behavior, such superparaelectric behavior is obviously a consequence of nanominiaturization of LiTaO3 crystal and insignificant cooperative interactions between the nanoparticles.

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