Selenium-loaded zeolite (ZSM-5): II. Photoinduced phenomena

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Description

Photoinduced phenomena in Se-loaded ZSM-5 single crystals have been studied through electron-spin resonance, optical absorption, and photoluminescence spectroscopy. Marked exposure effects appear at room temperature. Upon illumination of visible light, an electron-spin signal at g [approximate to] 2.00 increases by an order, subgap absorption of 10^3 cm^[-1] appears, and photoluminescence at subgap regions weakens to a half. Timescales of these photoinduced changes including recoveries are not the same, which suggests different origins for the three changes. The spin increase evinces bond scission in single Se chains. © 2009 American Institute of Physics

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Details 詳細情報について

  • CRID
    1050001339000982912
  • NII Article ID
    120001415114
  • DOI
    10.1063/1.3143612
  • ISSN
    10897550
    00218979
  • HANDLE
    2115/38779
  • Text Lang
    en
  • Article Type
    journal article
  • Data Source
    • IRDB
    • CiNii Articles
    • OpenAIRE

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