Structure Selectivity of Space Fullerene Materials

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  • 立体フラーレン型化合物の構造選択則
  • リッタイ フラーレンガタ カゴウブツ ノ コウゾウ センタクソク

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A fundamental principle on the crystal structure selectivity for the clathrate materials is derived from the standard theory on the stability of the clathrate hydrates and the empirical rule for the Frank-Kasper phases of alloys. It explains why the number of naturally-occurring clathrate structures is limited out of a diversity of possible structures and proposes a guideline to explore the new crystal structures.

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