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[Abstract] Phase diagram of binary system CTAB (cetyltrimethylammonium bromide) : OIPh (o-iodophenol) was investigated by DSC, TG methods along with polarizing-microscopic and visual observations. Owing to the large difference in cohesive energy and volatility between the two component substances, the phase behavior is rather complex particularly in the CTAB-rich region. It was found that CTAB and OIPh produce 1: 3 intermolecular complex in addition to the 1: 1 complex already reported. Both of the complexes undergo incongruent melting at about 305 K and 365 K, respectively. Formation of another 2: 1 complex in the high temperature region is proposed. The 2: 1 complex produces solid solution of mesomorphic nature in a limited composition range with the high-temperature metastable phase of CTAB. Thermodynamics of formation of the 1: 1 complex in the crystalline state is discussed.
Departmental Bulletin Paper
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収録刊行物
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- 理工学総合研究所研究報告
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理工学総合研究所研究報告 (11), 5-13, 1999-02-28
近畿大学理工学総合研究所
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詳細情報 詳細情報について
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- CRID
- 1050007779701657088
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- NII論文ID
- 40004826033
- 120007144697
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- NII書誌ID
- AN10074306
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- ISSN
- 09162054
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- NDL書誌ID
- 4680791
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- 本文言語コード
- en
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- 資料種別
- departmental bulletin paper
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- データソース種別
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- IRDB
- NDL
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