Nitro–Nitrito Photoisomerization of Platinum(II) Complexes with Pt(NO<sub>2</sub>)<sub>4</sub><sup>2–</sup> and (FSO<sub>2</sub>)<sub>2</sub>N<sup>–</sup> Anions: Correlation between Isomerization Ratio and Reaction Cavity
書誌事項
- タイトル別名
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- Nitro–Nitrito Photoisomerization of Platinum(II) Complexes with Pt(NO2)42– and (FSO2)2N– Anions: Correlation between Isomerization Ratio and Reaction Cavity
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抄録
Nitro–nitrito linkage isomerization is a well-known photochemical reaction of metal complexes in the solid state. To quantitatively elucidate the influence of the crystal environment on this reaction, we synthesized salts of a cationic platinum(II) nitrito complex with Pt(NO2)42– and (FSO2)2N– anions (1-Pt(NO2)4 and 1-FSA, respectively). Their thermal properties and photoreactivities were investigated, and the linkage isomerization of the cations and the Pt(NO2)4 anion upon ultraviolet photoirradiation at 180 K was observed by X-ray structural analysis. The isomerization levels for the cations in 1-Pt(NO2)4 and 1-FSA were 49% and 80%, respectively, and that for the Pt(NO2)4 anion was in the range of 0–65%. The conversion was correlated with the reaction cavity size surrounding the NO2 ligands.
収録刊行物
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- Crystal Growth & Design
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Crystal Growth & Design 20 (12), 8047-8052, 2020-12-02
American Chemical Society
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詳細情報 詳細情報について
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- CRID
- 1050012570392208896
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- NII論文ID
- 120006952744
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- NII書誌ID
- AA1150352X
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- ISSN
- 15287505
- 15287483
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- HANDLE
- 20.500.14094/90007778
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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