Graphene oxide-fullerene nanocomposite laminates for efficient hydrogen purification

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Graphene oxide (GO) with its unique two-dimensional structure offers an emerging platform for designing advanced gas separation membranes that allow for highly selective transport of hydrogen molecules. Nevertheless, further tuning of the interlayer spacing of GO laminates and its effect on membrane separation efficiency remains to be explored. Here, positively charged fullerene C₆₀ derivatives are electrostatically bonded to the surface of GO sheets in order to manipulate the interlayer spacing between GO nanolaminates. The as-prepared GO-C₆₀ membranes have a high H₂ permeance of 3370 GPU (gas permeance units) and an H₂/CO₂ selectivity of 59. The gas separation selectivity is almost twice that of flat GO membranes because of the role of fullerene.

収録刊行物

  • Chemical Communications

    Chemical Communications 59 (66), 10012-10015, 2023-08-25

    Royal Society of Chemistry (RSC)

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詳細情報 詳細情報について

  • CRID
    1050015897173951616
  • ISSN
    1364548X
    13597345
  • HANDLE
    2433/284856
  • 本文言語コード
    en
  • 資料種別
    journal article
  • データソース種別
    • IRDB

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