Denary High-Entropy Oxide Nanoparticles Synthesized by a Continuous Supercritical Hydrothermal Flow Process

機関リポジトリ (HANDLE) オープンアクセス
  • 花畑, 翔太
    Division of Chemistry, Graduate School of Science, Kyoto University
  • 草田, 康平
    Division of Chemistry, Graduate School of Science, Kyoto University; The HAKUBI Center for Advanced Research, Kyoto University
  • 鳥山, 誉亮
    The Ultramicroscopy Research Center, Kyushu University
  • 山本, 知一
    The Ultramicroscopy Research Center, Kyushu University
  • 松村, 晶
    The Ultramicroscopy Research Center, Kyushu University; Department of Applied Quantum Physics and Nuclear Engineering, Kyushu University
  • 河口, 彰吾
    Center for Synchrotron Radiation Research, Japan Synchrotron Radiation Research Institute (JASRI), SPring-8
  • 久保田, 佳基
    Department of Physics, Graduate School of Science, Osaka Metropolitan University
  • 西田, 吉秀
    Advanced Ceramics Research Center, Nagoya Institute of Technology
  • 羽田, 政明
    Advanced Ceramics Research Center, Nagoya Institute of Technology
  • 北川, 宏
    Division of Chemistry, Graduate School of Science, Kyoto University

書誌事項

公開日
2024-01-10
資源種別
journal article
権利情報
  • This document is the Accepted Manuscript version of a Published Work that appeared in final form in 'Journal of the American Chemical Society', copyright © 2023 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.3c07351
  • The full-text file will be made open to the public on December 28, 2024 in accordance with publisher's 'Terms and Conditions for Self-Archiving'.
  • This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
公開者
American Chemical Society (ACS)

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説明

High-entropy oxide nanoparticles (HEO NPs) have been intensively studied because of their attractive properties, such as high stability and enhanced catalytic activity. In this work, for the first time, denary HEO NPs were successfully synthesized using a continuous supercritical hydrothermal flow process without calcination. Interestingly, this process allows the formation of HEO NPs on the order of seconds at a relatively lower temperature. The synthesized HEO NPs contained 10 metal elements, La, Ca, Sr, Ba, Fe, Mn, Co, Ru, Pd, and Ir, and had a perovskite-type structure. Atomic-resolution high-angle annular dark-field scanning transmission electron microscopy and energy-dispersive X-ray spectroscopy measurements revealed homogeneous dispersion of the 10 metal elements. The obtained HEO NPs also exhibited a higher catalytic activity for the CO oxidation reaction than that of the LaFeO₃ NPs.

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詳細情報 詳細情報について

  • CRID
    1050017345552242944
  • ISSN
    15205126
    00027863
  • HANDLE
    2433/286580
  • 本文言語コード
    en
  • 資料種別
    journal article
  • データソース種別
    • IRDB

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