A new strategy to exploit maximum rate performance for aqueous batteries through a judicious selection of MOF-type electrodes
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- 中本, 康介
- 九州大学先導物質化学研究所
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- Bai, Junwen
- 九州大学大学院総合理工学府
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- Zhao, Minyan
- 九州大学大学院総合理工学府
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- サカモト, リョウ
- 九州大学先導物質化学研究所
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- 趙, 麗巍
- 九州大学先導物質化学研究所
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- 伊藤, 正人
- 九州大学先導物質化学研究所
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- 岡田, 重人
- 九州大学先導物質化学研究所
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- 山本, 英治
- 九州大学大学院理学研究院化学部門
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- 村山, 美乃
- 九州大学大学院理学研究院化学部門
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- 徳永, 信
- 九州大学大学院理学研究院化学部門
説明
A metal–organic framework (MOF) having a redox active 1,4,5,8-naphthalenetetracarboxdiimide (NDI) derivative in its organic linker shows excellent rate performance as an electrode material for aqueous batteries thanks to its large pores. Among aqueous electrolytes examined, K+-based ones exhibit the highest rate performance, which is caused by the highest mobility of the smallest hydrated K+ ion not only in the aqueous electrolyte but also in the electrode. Since the use of a counter electrode with insufficiently small pores for the full-cell configuration offsets this merit, our study may lead to a conclusion that the maximum rate performance for aqueous batteries will be accomplished only through further elaboration of both electrode materials with sufficiently large pores, in which hydrated ions can travel equally fast as those in the electrolyte.
収録刊行物
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- RSC Advances
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RSC Advances 13 (32), 22070-22078, 2023
Royal Society of Chemistry (RSC)
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詳細情報 詳細情報について
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- CRID
- 1050018971027089792
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- ISSN
- 20462069
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- HANDLE
- 2324/7178880
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- PubMed
- 37483666
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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