Chiral Recognition in the Inclusion Complex of Cyclodextrins with N-Dansyl-Phenylalanine Observed by Linked Scan FAB-MS Spectrometry

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The cyclodextrin (CD) inclusion complex showed a chiral recognition observed by linked scan FAB-MS. The ratio, R, of the daughter ionic peak strength to the precursor ionic peak strength using the linked scan FAB-MS method was suggested to express a parameter for the stability of CD inclusion complex. The ratios between R_D and R_L were determined in inclusion complexes consisted of D-and L-N-dansyl-phenylalanines with various CDs. As for this parameter R derived from the linked scan FAB-MS ionic peaks, the wide application is possible to the inclusion complexes and the evaluation of the chiral recognition in various inclusion complexes.

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KJ00001512088

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