Synthesis of disubstituted homodiamantanes by acylative ring expansion using benzoyl trifluoromethanesulfonate
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Description
Diamantane is a hydrocarbon whose carbon framework is a part of diamond lattices. Acylative ring expansion of 1- and 4-diamantanecarbaldehyde using benzoyl trifluoromethanesulfonate and trifluoromethanesulfonic acid yielded 10-hydroxyhomodiamant-9-yl benzoate and 7-hydroxyhomodiamant-8-yl benzoate, whose skeletal structures are same as pentacyclo[8.3.1.1^(4,13).0^(2,7).0^(6,12)]tetradecane.
Journal
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- Science and technology of advanced materials
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Science and technology of advanced materials 7 (6), 531-535, 2006-09-01
Elsevier
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Details 詳細情報について
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- CRID
- 1050282677912572032
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- NII Article ID
- 120001037069
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- NII Book ID
- AA11561821
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- HANDLE
- 10076/9310
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- ISSN
- 14686996
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- CiNii Articles