ChemInform Abstract: Molecular Recognition of Ketomalonates by Asymmetric Aldol Reaction of Aldehydes with Secondary‐Amine Organocatalysts.
書誌事項
- タイトル別名
-
- Molecular recognition of ketomalonates by asymmetric aldol reaction of aldehydes with secondary-amine organocatalysts.
- 公開日
- 2012-05
- 資源種別
- journal article
- 権利情報
-
- © The Royal Society of Chemistry
- This is not the published version. Please cite only the published version.
- この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
- DOI
-
- 10.1039/c2cc32772d
- 10.1002/chin.201245028
- 公開者
- Royal Society of Chemistry
この論文をさがす
説明
A diastereo- and enantioselective aldol reaction between aldehydes and a synthetically useful ketomalonate 1c as a hydrated form was developed, and either anti- or syn-aldol adducts having a chiral tetrasubstituted carbon center were obtained in high enantioselectivities by use of a tetrazole analogue of L-proline (S)-2 or an axially chiral amino sulfonamide (S)-3 as catalyst.
収録刊行物
-
- Chemical communications
-
Chemical communications 48 7037-7039, 2012-05
Royal Society of Chemistry
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1050282810746558336
-
- NII論文ID
- 120005245150
-
- NII書誌ID
- AA12455105
-
- ISSN
- 1364548X
- 15222667
- 13597345
- 09317597
-
- HANDLE
- 2433/174340
-
- PubMed
- 22684237
-
- 本文言語コード
- en
-
- 資料種別
- journal article
-
- データソース種別
-
- IRDB
- Crossref
- CiNii Articles
- KAKEN
- OpenAIRE
