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Reactivity of Highly Lewis-Acidic Diborane(4) toward C≡N and N=N Bonds: Uncatalyzed Addition and N=N Bond-Cleavage Reactions
Bibliographic Information
- Other Title
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- Reactivity of Highly Lewis‐Acidic Diborane(4) toward C≡N and N=N Bonds: Uncatalyzed Addition and N=N Bond‐Cleavage Reactions
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Description
The diboration of the C≡N bond in organic nitriles, and the N=N bond in azobenzene and pyridazine, by the highly Lewis‐acidic tetra(o‐tolyl)diborane(4) are reported. In the reactions with nitriles, azobenzene, and pyridazine, the addition of diborane(4) to the C≡N and N=N bonds was observed. Conversely, the N=N bond in phthalazine was cleaved by an addition/rearomatization sequence.
Journal
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 58 (1), 317-321, 2019-01-02
Wiley
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Details 詳細情報について
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- CRID
- 1050282813790655616
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- NII Article ID
- 120006623783
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- ISSN
- 15213773
- 15213757
- 14337851
- 00448249
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- HANDLE
- 2237/00030114
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- PubMed
- 30430694
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- Web Site
- https://nagoya.repo.nii.ac.jp/records/27915
- https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201812692
- http://api.wiley.com/onlinelibrary/chorus/v1/articles/10.1002%2Fanie.201812692
- https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201812692
- https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fange.201812692
- http://api.wiley.com/onlinelibrary/chorus/v1/articles/10.1002%2Fange.201812692
- https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201812692
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- Crossref
- CiNii Articles
- KAKEN
- OpenAIRE