PALLADIUM-CATALYZED AMINATION OF 2-CHLORO-1-AZAAZULENE WITH 2-AMINOPYRIDINE

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Description

Palladium-catalyzed amination of 2-chloro-1-azaazulene with 2-aminopyridine was studied under various conditions in order to obtain N-(1-azaazulen-2-yl)-N-(2-pyridyl)amine (4) and N,N-bis(1-azaazillen-2-yl)-N-(2-pyridyl)amine (5) as a multidentate ligand. Results of the reaction and physical and chemical properties of 4 and 5 are described.

Journal

  • HETEROCYCLES

    HETEROCYCLES 83 (3), 547-554, 2011-03

    The Japan Institute of Heterocyclic Chemistry

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