High-pressure dc magnetic measurements on a bisdiselenazolyl radical ferromagnet using a vibrating-coil SQUID magnetometer
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Abstract
The high-pressure magnetic properties of the iodo-substituted bisdiselenazolyl radical ferromagnet IBPSSEt have been studied by vibrating-coil SQUID magnetometry. The magnetic state at a pressure (P) of approximately 2 GPa has the highest Curie temperature (TC) of 27.5 K, and displays an ideal three-dimensional (3D) ferromagnetic interaction network. The value of TC observed by ac magnetic susceptibility measurements is consistent with that obtained from dc measurements below approximately 4 GPa. Field-cooled dc measurements at more elevated pressures reveal a slow evolution of magnetic ordering, so that atP >6 GPa the structure may be described in terms of a 1D ferromagnetic chain with predominantly antiferromagnetic lateral (interchain) interactions, in accord with the results of density functional theory calculations.
Journal
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- Physical Review B
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Physical Review B 99 (1), 014417-1-014417-7, 2019-01-17
American Physical Society
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Details 詳細情報について
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- CRID
- 1050282813915379584
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- NII Article ID
- 120006591354
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- NII Book ID
- AA11187113
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- ISSN
- 24699969
- 24699950
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- HANDLE
- 10228/00007077
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- Crossref
- CiNii Articles
- KAKEN