Concise [4+3] cycloaddition reaction of pyrroles leading to tropinone derivatives
説明
A concise [4+3] cycloaddition reaction of pyrroles with 2-(silyloxy)allyl cations has been developed. The oxyallyl cations stabilized with a methylthio group or geminal methyl groups were generated from the corresponding allylic alcohols under the influence of a Brönsted acid (Tf2NH), respectively. The use of N-nosyl-protected pyrroles as the four-carbon unit was found to give tropinone derivatives in high yield.
収録刊行物
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- Tetrahedron Letters
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Tetrahedron Letters 53 (43), 5725-5728, 2012-10-24
Elsevier
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詳細情報 詳細情報について
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- CRID
- 1050282813988714368
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- NII論文ID
- 120004883875
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- HANDLE
- 2115/50425
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- ISSN
- 00404039
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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