Concise [4+3] cycloaddition reaction of pyrroles leading to tropinone derivatives
抄録
A concise [4+3] cycloaddition reaction of pyrroles with 2-(silyloxy)allyl cations has been developed. The oxyallyl cations stabilized with a methylthio group or geminal methyl groups were generated from the corresponding allylic alcohols under the influence of a Brönsted acid (Tf2NH), respectively. The use of N-nosyl-protected pyrroles as the four-carbon unit was found to give tropinone derivatives in high yield.
収録刊行物
-
- Tetrahedron Letters
-
Tetrahedron Letters 53 (43), 5725-5728, 2012-10-24
Elsevier
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1050282813988714368
-
- NII論文ID
- 120004883875
-
- HANDLE
- 2115/50425
-
- ISSN
- 00404039
-
- 本文言語コード
- en
-
- 資料種別
- journal article
-
- データソース種別
-
- IRDB
- Crossref
- CiNii Articles
- KAKEN