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Local structure around arsenic atoms in K-T boundary clays was studied by As K-edge XAFS spectroscopy. The threshold E0 energy of As and the characterization of the white peak of XANES spectra agree well with the values of As(+5) minerals like Zn2(AsO4)2(OH) 22H2O and CaCu(AsO4)(OH) according to the comparison with several types of arsenic minerals. This indicates that arsenic is in a high oxidation state As(+5) and occupies the AsO4 tetrahedral site of a mineral in K-T boundary clays.

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