Alkoxymigration onto alpha-Imino Gold Carbenes for Constructing Propellane-Type Indolines

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Description

We developed a new reaction entity of α-imino gold carbenes involving alkoxy migration. The reaction would proceed through oxonium ylide formation by intramolecular addition of an alkoxy group, carbon-oxygen bond cleavage, and carbon−carbon bond formation. We achieved an efficient gold-catalyzed synthesis of indoline-propellanes via a one-pot sequence by using ethylene glycol as a trapping reagent.

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Details 詳細情報について

  • CRID
    1050297372150652032
  • ISSN
    21935815
    21935807
  • HANDLE
    2433/284889
  • Text Lang
    en
  • Article Type
    journal article
  • Data Source
    • IRDB

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