Safe, One-Pot, Homogeneous Direct Synthesis of H_2O_2

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  • Ogo, Seiji
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University Center for Small Molecule Energy, Kyushu University
  • Yatabe, Takeshi
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University Center for Small Molecule Energy, Kyushu University
  • Tome, Tamon
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Takenaka, Riko
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Shiota, Yoshihito
    International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University
  • Kato, Kenji
    Center for Small Molecule Energy, Kyushu University Mitsubishi Gas Chemical Company Inc.

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  • Safe, One-Pot, Homogeneous Direct Synthesis of H<sub>2</sub>O<sub>2</sub>

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This paper reports the first example of a reductive C(sp^3)–C(sp^3) homo-coupling of benzyl/allyl halides in aqueous solution by using H_2 as an electron source {turnover numbers (TONs) = 0.5–2.3 for 12 h}. This homo-coupling reaction, promoted by visible light, is catalysed by a water-soluble electron storage catalyst (ESC). The reaction mechanism, and four requirements to make it possible, are also described.

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